Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones

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	Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones
	Hang XC(杭晓春) ; Gu WP(顾伟鹏) ; Chen QY(陈庆云) ; Xiao JC(肖吉昌)
刊名	Tetrahedron
	2009
卷号	65 期号:32 页码:6320-6324
ISSN号	0040-4020
其他题名	二氟卡宾和炔基酯的反应以及二氟环丙基酮的高效合成
通讯作者	肖吉昌
英文摘要	Difluorocarbene generated from FSO2CF2CO2SiMe3 (TFDA) at 120 degrees C could reacted with terminal alkynes having an ester group at the a position to the triple bond. Difluorocyclopropenes were further converted to difluorocyclopropyl ketones under alkaline condition. Mechanism for the conversion was studied. (C) 2009 Elsevier Ltd. All rights reserved.
学科主题	有机氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tet.2009.06.019
语种	英语
WOS记录号	WOS:000268736900005
公开日期	2013-01-17
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/13672]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Hang XC,Gu WP,Chen QY,et al. Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones[J]. Tetrahedron,2009,65(32):6320-6324.
APA	杭晓春,顾伟鹏,陈庆云,&肖吉昌.(2009).Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones.Tetrahedron,65(32),6320-6324.
MLA	杭晓春,et al."Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones".Tetrahedron 65.32(2009):6320-6324.