Synthesis and Electrochemical Characterizations of Zinc-doped LiFePO4/C by Carbothermal Reduction

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	Synthesis and Electrochemical Characterizations of Zinc-doped LiFePO4/C by Carbothermal Reduction
	Hua Ning; Wang Chen-Yun; Kang Xue-Ya; Tuerdi; Han Ying
刊名	JOURNAL OF INORGANIC MATERIALS
	2010
卷号	25 期号:8 页码:887-892
关键词	LiFePO4 doping zinc lithium ion battery cycle performance
ISSN号	1000324X
通讯作者	Kang, XY
英文摘要	Alien atom doping has been adopted to modify the electrochemical performance of olivine type LiFePO4 for cathode material. Here, we report that zinc-doping can improve the performance of LiFePO4/C immensely by a simple method. LiFePO4/C and Zn-doped LiFePO4/C cathode materials were firstly synthesized by carbothermal reduction method. Physical-chemical characterizations were done by X-ray diffraction, scanning electron microscope and transmittance electron microscope. Electrochemical behavior of the cathode materials were analyzed by using cyclic voltammetry, and galvanostatic measurements were employed to characterize the reaction of lithium ion insertion and de-insertion. ICP and XRD analyses indicate that Zn ions were sufficiently doped in LiFePO4 and did not alter its crystal structure. During de-intercalation and intercalation process of lithium ions, the doped zinc atoms protect the LiFePO4 crystal from shrink. Consequently, the conductivity is enhanced after doping. It is noted that zinc ions doping can improve performance of LiFePO4, especially on the aspect of stable cycle-life at higher C rate.
学科主题	Materials Science
收录类别	SCI
WOS记录号	WOS:000282117400020
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1856]
专题	新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
推荐引用方式 GB/T 7714	Hua Ning,Wang Chen-Yun,Kang Xue-Ya,et al. Synthesis and Electrochemical Characterizations of Zinc-doped LiFePO4/C by Carbothermal Reduction[J]. JOURNAL OF INORGANIC MATERIALS,2010,25(8):887-892.
APA	Hua Ning,Wang Chen-Yun,Kang Xue-Ya,Tuerdi,&Han Ying.(2010).Synthesis and Electrochemical Characterizations of Zinc-doped LiFePO4/C by Carbothermal Reduction.JOURNAL OF INORGANIC MATERIALS,25(8),887-892.
MLA	Hua Ning,et al."Synthesis and Electrochemical Characterizations of Zinc-doped LiFePO4/C by Carbothermal Reduction".JOURNAL OF INORGANIC MATERIALS 25.8(2010):887-892.