Synthesis, structure characterization and optical properties of a new lead cadmium borate

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Synthesis, structure characterization and optical properties of a new lead cadmium borate
	Yu Hongwei; Pan Shilie; Wu Hongping; Han Jian; Li Hongyi; Yang Zhihua
刊名	INORGANICA CHIMICA ACTA
	2012
卷号	384 期号:4 页码:158-162
关键词	Pb3Cd3(BO3)(4) Borate Synthesis Crystal structure Optical property
ISSN号	0020-1693
通讯作者	Pan, SL
中文摘要	A new ternary borate, Pb3Cd3(BO3)(4), has been synthesized by solid-state reaction at 530 degrees C. The compound crystallizes in the hexagonal space group P6(3)/m with a = 9.946(4), c = 7.003(5) angstrom, and Z = 2. The crystal structure consists of one-dimensional (1D) long PbO5(infinity) tubes. The tubes are further connected by BO3 to generate a three-dimensional framework with the six-member tunnels along the c axis, where Cd atoms locate and the CdO6 octahedra form 1D chain. The IR spectrum confirms the presence of BO3 unit. The UV-Vis-IR diffuse reflectance spectrum exhibits a band gap of about 3.56 eV. The DSC analysis suggests that Pb3Cd3(BO3)(4) is an incongruent melting compound.
学科主题	Chemistry
收录类别	SCI
资助信息	Chinese Academy of Sciences KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; Scientific Research Program of Urumqi of China G09212001
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1631]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yu Hongwei,Pan Shilie,Wu Hongping,et al. Synthesis, structure characterization and optical properties of a new lead cadmium borate[J]. INORGANICA CHIMICA ACTA,2012,384(4):158-162.
APA	Yu Hongwei,Pan Shilie,Wu Hongping,Han Jian,Li Hongyi,&Yang Zhihua.(2012).Synthesis, structure characterization and optical properties of a new lead cadmium borate.INORGANICA CHIMICA ACTA,384(4),158-162.
MLA	Yu Hongwei,et al."Synthesis, structure characterization and optical properties of a new lead cadmium borate".INORGANICA CHIMICA ACTA 384.4(2012):158-162.