Structure, growth and properties of a novel polar material, KSr4B3O9

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Structure, growth and properties of a novel polar material, KSr4B3O9
	Zhao Wenwu; Pan Shilie; Wang Yongjiang; Yang Zhihua; Wang Xian; Han Jian
刊名	Journal of Solid State Chemistry
	2012
卷号	195 期号:11 页码:73-78
关键词	Polar material Structure Growth Optical properties Theoretical calculation
ISSN号	224596
通讯作者	Pan, SL
中文摘要	A novel polar material, KSr4B3O9, has been obtained by the high temperature solution method for the first time. It crystallizes in the polar space group Ama2. The material exhibits a three-dimensional structure consisting of interconnecting KO10 groups, SrOx (x=8, 9) units and isolated BO3 triangles. DSC/TG curve shows that KSr4B3O9 melts incongruently. The calculated band structures and the density of states of KSr4B3O9 suggest that its direct gap is 3.897 eV. The absorption spectrum indicates the absorption edge of KSr 4B3O9 is about 302 nm. It produces SHG intensity about as large as that of KH2PO4 (KDP) and is phase matchable.
收录类别	SCI
资助信息	National Natural Science Foundation of China U1129301, 51172277, 50802110, 21101167, 21101168, 11104344; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201130111; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 201116143
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1378]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China;Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion SINANO, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Zhao Wenwu,Pan Shilie,Wang Yongjiang,et al. Structure, growth and properties of a novel polar material, KSr4B3O9[J]. Journal of Solid State Chemistry,2012,195(11):73-78.
APA	Zhao Wenwu,Pan Shilie,Wang Yongjiang,Yang Zhihua,Wang Xian,&Han Jian.(2012).Structure, growth and properties of a novel polar material, KSr4B3O9.Journal of Solid State Chemistry,195(11),73-78.
MLA	Zhao Wenwu,et al."Structure, growth and properties of a novel polar material, KSr4B3O9".Journal of Solid State Chemistry 195.11(2012):73-78.