A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12
	Chen Songjie; Pan Shilie; Zhao Wenwu; Yu Hongwei; Wu Hongping; Yang Zhihua; Yang Yun
刊名	Dalton Transactions
	2012
卷号	41 期号:30 页码:9202-9208
ISSN号	14779226
通讯作者	Pan, SL
中文摘要	A new noncentrosymmetric vanadoborate compound, K2SrVB 5O12, is synthesized by the high temperature solution method. It crystallizes in the monoclinic space group P21 (no. 4) with lattice constants a = 6.618(3) A˚, b = 8.378(4) A˚, c = 9.974(5) A˚, β = 99.789(6)°, Z = 2. The structure consists of vanadoborate anionic layers with K⁺ and Sr²⁺ cations filling the void spaces via electrostatic interactions to form the three-dimensional network. The TG-DSC curves and the UV-Vis-NIR diffuse reflectance spectrum were measured. Band structures and density of states were calculated. The powder second harmonic generation (SHG) effect of K2SrVB5O12 is similar to that of KH2PO4 (KDP).
学科主题	Chemistry
收录类别	SCI
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1372]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Chen Songjie,Pan Shilie,Zhao Wenwu,et al. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12[J]. Dalton Transactions,2012,41(30):9202-9208.
APA	Chen Songjie.,Pan Shilie.,Zhao Wenwu.,Yu Hongwei.,Wu Hongping.,...&Yang Yun.(2012).A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12.Dalton Transactions,41(30),9202-9208.
MLA	Chen Songjie,et al."A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12".Dalton Transactions 41.30(2012):9202-9208.