Efficient synthesis of glycerol carbonate from glycerol and urea with lanthanum oxide as a solid base catalyst | |
Liu SM(刘士民); Deng YQ(邓友全); Deng YQ(邓友全); Wang Y(王瀛) | |
刊名 | Catalysis Communications |
2011 | |
卷号 | 12页码:1458-1462 |
关键词 | Glycerol carbonate Urea Glycerol Lanthanum oxide Solid base |
ISSN号 | 1566-7367 |
通讯作者 | 邓友全 |
中文摘要 | Lanthanum oxide catalyst prepared by precipitation method and calcined at 600 °C exhibited better catalytic activity in the catalytic synthesis of glycerol carbonate from glycerol and urea with TOF up to 1506 mmol/g·h. It was proposed that the lanthanum oxide catalyst with more strong basic sites (TdN400 °C) exhibited higher catalytic activity. Accordingly, the catalyst containing appropriate amount of La2O2CO3 phase exhibited higher catalytic activity. Moreover, the recycling experiments demonstrated that the catalytic activity can be essentially preserved during the recycling tests investigated. |
学科主题 | 物理化学 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000294507700015 |
公开日期 | 2012-12-04 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/2365] |
专题 | 兰州化学物理研究所_绿色化学研究发展中心 |
通讯作者 | Deng YQ(邓友全); Deng YQ(邓友全) |
推荐引用方式 GB/T 7714 | Liu SM,Deng YQ,Deng YQ,et al. Efficient synthesis of glycerol carbonate from glycerol and urea with lanthanum oxide as a solid base catalyst[J]. Catalysis Communications,2011,12:1458-1462. |
APA | 刘士民,邓友全,邓友全,&王瀛.(2011).Efficient synthesis of glycerol carbonate from glycerol and urea with lanthanum oxide as a solid base catalyst.Catalysis Communications,12,1458-1462. |
MLA | 刘士民,et al."Efficient synthesis of glycerol carbonate from glycerol and urea with lanthanum oxide as a solid base catalyst".Catalysis Communications 12(2011):1458-1462. |
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