Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 绿色化学研究发展中心

	Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites
	Deng YQ(邓友全); He YD(何昱德); Lu LJ(卢六斤); Zhang QH(张庆华); Shi F(石峰); Shi F(石峰); Ma XY(马祥元)
刊名	Chinese Journal of Catalysis
	2010
卷号	31 期号:8 页码:933-937
关键词	active site ionic liquid metal complex carbonylation aniline phenyl methyl carbamate turnover frequency
ISSN号	0253-9837
通讯作者	邓友全 ; 石峰
中文摘要	The integration of a free metal complex, Pd(phen)2+, and a room temperature ionic liquid (IL) solvent molecule, 1-decyl-3-methyl imidazolium bromide, into a complete catalytically active site and confined in a NaY zeolite super-cage with an appropriate spatial arrangement was investigated. This integration was achieved through a molecular self-assembly method. A preliminary test of this catalyst system for the carbonylation of aniline to methyl phenyl carbamate indicated that far higher catalytic activity could be achieved (TOF increased from 3 000 to 23 000 h–1) with far lower amounts of the IL solvent and the Pd complex in comparison with a simple mixture of Pd(phen)Cl2/IL/NaY as the catalyst. This new system can also be applied to other areas of catalysis.
学科主题	物理化学
收录类别	CSCD
语种	英语
CSCD记录号	CSCD:3987731
WOS记录号	WOS:000282079400008
公开日期	2012-11-14
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/2208]
专题	兰州化学物理研究所_绿色化学研究发展中心
通讯作者	Deng YQ(邓友全); Shi F(石峰); Shi F(石峰)
推荐引用方式 GB/T 7714	Deng YQ,He YD,Lu LJ,et al. Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites[J]. Chinese Journal of Catalysis,2010,31(8):933-937.
APA	邓友全.,何昱德.,卢六斤.,张庆华.,石峰.,...&马祥元.(2010).Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites.Chinese Journal of Catalysis,31(8),933-937.
MLA	邓友全,et al."Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites".Chinese Journal of Catalysis 31.8(2010):933-937.