Removal of congo red from aqueous solution by adsorption on organified rectorite
Liu Y(刘毅); Wang WB(王文波); Wang AQ(王爱勤)
刊名CLEAN - Soil, Air, Water
2010
卷号38期号:7页码:670-677
关键词Congo red Dyes Kinetics Rectorite Sorption isotherm
ISSN号1863-0650
通讯作者王爱勤 aqwang@licp.cas.cn
中文摘要Batch sorption technique was carried out for the removal of anionic dye Congo red (CR) from aqueous solution using raw rectorite (R-REC) and organified rectorite (CTAþ-REC) modified by cetyltrimethylammonium bromide (CTAB) as adsorbents. The effects of organification degree of CTAþ-REC as well as the process parameters including the pH of dye solution, sorption time, and initial dye concentration on adsorption capacity for CR were investigated and the sorption kinetics was also evaluated. The results showed that the sorption behaviors of R-REC and CTAþ-REC for CR followed pseudo-second-order kinetic model and the sorption equilibrium data perfectly obeyed the Langmuir isotherm. The thermodynamic parameters including entropy of sorption (DS0), enthalpy of sorption (DH0), and Gibbs free energy of sorption (DG0) were obtained and analyzed. Fourier transform infrared study revealed that a chemisorption process occurred between CR and CTAþ-REC. REC modified by cationic surfactants showed the higher adsorption capacities for CR compared to R-REC and in theory would be used as an efficient and promising adsorbent for the removal of anionic dyes in wastewater treatment.
学科主题功能高分子
收录类别SCI
资助信息江苏省科技厅项目(BE2008087)
语种英语
公开日期2012-09-02
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/135]  
专题兰州化学物理研究所_环境材料与生态化学研究发展中心
推荐引用方式
GB/T 7714
Liu Y,Wang WB,Wang AQ. Removal of congo red from aqueous solution by adsorption on organified rectorite[J]. CLEAN - Soil, Air, Water,2010,38(7):670-677.
APA 刘毅,王文波,&王爱勤.(2010).Removal of congo red from aqueous solution by adsorption on organified rectorite.CLEAN - Soil, Air, Water,38(7),670-677.
MLA 刘毅,et al."Removal of congo red from aqueous solution by adsorption on organified rectorite".CLEAN - Soil, Air, Water 38.7(2010):670-677.
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