Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-k2N,N´) cobalt(II) dichloromethane hemisolvate

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	Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-k2N,N´) cobalt(II) dichloromethane hemisolvate
	Yang PJ(杨培菊)
刊名	Acta Crystallographica Section E
	2008
卷号	E64 页码:m623
关键词	single-crystal X-ray study T = 293 K mean σ(C–C) = 0.007 Å R factor = 0.056 wR factor = 0.160 data-to-parameter ratio = 17.7
ISSN号	1600-5368
通讯作者	吴彪
中文摘要	The title compound, [CoCl2(C21H17ClN2)] 0.5CH2Cl2, crystallizes from dichloromethane as a 2:1 solvate [CoCl2L]2 CH2Cl2 (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl2L molecules in the asymmetric unit and both molecules have similar conformations. They are connected by a weak C—H…p interaction involving the mesityl ring. The cobalt center is four-coordinated by the two N-atom donors of the bidentate ligand and two chloride ions in a distorted tetrahedral geometry. The packing of the molecules is stabilized by weak slipped p–p stacking interactions between symmetry-related phenanthroline groups.
学科主题	金属有机与超分子催化
收录类别	SCI
语种	英语
公开日期	2012-11-09
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/1948]
专题	兰州化学物理研究所_OSSO国家重点实验室
推荐引用方式 GB/T 7714	Yang PJ. Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-k2N,N´) cobalt(II) dichloromethane hemisolvate[J]. Acta Crystallographica Section E,2008,E64:m623.
APA	杨培菊.(2008).Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-k2N,N´) cobalt(II) dichloromethane hemisolvate.Acta Crystallographica Section E,E64,m623.
MLA	杨培菊."Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-k2N,N´) cobalt(II) dichloromethane hemisolvate".Acta Crystallographica Section E E64(2008):m623.