Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines

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	Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines
	Song SJ(宋盛菊) ; Zhao WZ(赵炜珍) ; Wang L(王林) ; Carl Redshaw ; Wang FS(王佛松) ; Sun WH(孙文华)
刊名	J. Organomet. Chem.
	2011
卷号	696 页码:3029-3035
关键词	Ethylene dimerization 2-(1-Aryliminoethylidene)quinoline Cobalt Iron
ISSN号	0022-328X
通讯作者	孙文华
中文摘要	A series of 2-(1-aryliminoethylidene)quinolines (L) were synthesized and used as bidentate N^N ligands in coordinating with metal (cobalt and iron) chlorides to form complexes of the type LMCl2, cobalt(II) (Co1eCo5) and iron(II) (Fe1eFe5). All organic compounds and metal complexes were fully characterized, and the molecular structures of the representative complexes Co3$DMF and Fe4$DMF were confirmed as distorted bipyramidal geometry at the metal by single-crystal X-ray diffraction. Upon activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO) under 10 atm ethylene, all complexes showed high activities in ethylene dimerization with activities of up to 1.82 106 g mol 1 (Co) h 1 and 5.89 105 g mol 1 (Fe) h 1, respectively.
学科主题	物理化学
收录类别	SCI
资助信息	the MOST 863 program No. 2009AA033601
语种	英语
WOS记录号	WOS:000292726800015
公开日期	2012-09-20
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/388]
专题	兰州化学物理研究所_OSSO国家重点实验室
推荐引用方式 GB/T 7714	Song SJ,Zhao WZ,Wang L,et al. Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines[J]. J. Organomet. Chem.,2011,696:3029-3035.
APA	宋盛菊,赵炜珍,王林,Carl Redshaw,王佛松,&孙文华.(2011).Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines.J. Organomet. Chem.,696,3029-3035.
MLA	宋盛菊,et al."Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines".J. Organomet. Chem. 696(2011):3029-3035.