Ligand-Free Pd-Catalyzed Carbonylative Cross-Coupling Reactions under Atmospheric Pressure of Carbon Monoxide: Synthesis of Aryl Ketones and Heteroaromatic Ketones | |
Qi YX(齐彦兴); Yang M(杨敏) | |
刊名 | Eur. J. Org. Chem. |
2011 | |
页码 | 2662-2667 |
关键词 | Palladium Carbonylation Ketones Ligand-free Cross-coupling |
ISSN号 | 1434-193X |
通讯作者 | 杨敏 ; 薛继军 |
中文摘要 | The carbonylative Suzuki cross-coupling reactions of boronic acids with aryl iodides catalyzed by Pd2(dba)3 as a ligandfree catalyst under atmospheric pressure of carbon monoxide has been firstly developed. Under mild reaction conditions, a broad range of aryl/heteroaryl iodides and aryl/heteroaryl boronic acids were selectively coupled to afford the corresponding diaryl ketones in good to excellent yields at low catalyst loadings (0.05 to 2 mol-%). Moreover, the catalyst can also be recycled. |
学科主题 | 物理化学 |
收录类别 | SCI |
资助信息 | the Natural Science Foundation of Gansu Province (3ZS071-A25-009) |
语种 | 英语 |
WOS记录号 | WOS:000290655100008 |
公开日期 | 2012-09-20 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/375] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
通讯作者 | Yang M(杨敏) |
推荐引用方式 GB/T 7714 | Qi YX,Yang M. Ligand-Free Pd-Catalyzed Carbonylative Cross-Coupling Reactions under Atmospheric Pressure of Carbon Monoxide: Synthesis of Aryl Ketones and Heteroaromatic Ketones[J]. Eur. J. Org. Chem.,2011:2662-2667. |
APA | 齐彦兴,&杨敏.(2011).Ligand-Free Pd-Catalyzed Carbonylative Cross-Coupling Reactions under Atmospheric Pressure of Carbon Monoxide: Synthesis of Aryl Ketones and Heteroaromatic Ketones.Eur. J. Org. Chem.,2662-2667. |
MLA | 齐彦兴,et al."Ligand-Free Pd-Catalyzed Carbonylative Cross-Coupling Reactions under Atmospheric Pressure of Carbon Monoxide: Synthesis of Aryl Ketones and Heteroaromatic Ketones".Eur. J. Org. Chem. (2011):2662-2667. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论