Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst

	Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst
	Zeng, Ju-Lan 1; Yu, Sai-Bo 2; Cao, Zhong 1; Yang, Dao-Wu 1; Sun, Li-Xian 3; Zhang, Ling 1; Zhang, Xiong-Fei 1
刊名	journal of thermal analysis and calorimetry
	2011-09-01
卷号	105 期号:3 页码:961-968
关键词	Enantioselective catalyst Crystal structure Molar heat capacity Thermodynamic functions
ISSN号	1388-6150
通讯作者	zengjulan ; yusai-bo
产权排序	3,5
中文摘要	synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst
英文摘要	a new potential enantioselective catalyst derived from ferrocene, 1-{(r)-1-[(s)-2-(diphenylphosphino)ferrocenyl]ethyl}-benzimidazole (dpfeb), was prepared and its absolute structure was characterized by means of single crystal x-ray diffraction. the molar heat capacity of dpfeb was measured by means of temperature modulated differential scanning calorimetry over the temperature range of 200-530 k, and the thermodynamic functions of [h (t) - h (298.15)] and [s (t) - s (298.15)] were calculated. further more, thermogravimetry experiment revealed that dpfeb exhibited a three step thermal decomposition process with the final residual of 28.7%.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, analytical ; chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	ferrocene derivatives ; chiral ferrocenylphosphines ; asymmetric-synthesis ; ligands ; polymers
收录类别	SCI
语种	英语
WOS记录号	WOS:000294014000026
公开日期	2012-07-09
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/115758]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China 2.China Tobacco Hunan Ind Corp, Changsha 410007, Hunan, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zeng, Ju-Lan,Yu, Sai-Bo,Cao, Zhong,et al. Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst[J]. journal of thermal analysis and calorimetry,2011,105(3):961-968.
APA	Zeng, Ju-Lan.,Yu, Sai-Bo.,Cao, Zhong.,Yang, Dao-Wu.,Sun, Li-Xian.,...&Zhang, Xiong-Fei.(2011).Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst.journal of thermal analysis and calorimetry,105(3),961-968.
MLA	Zeng, Ju-Lan,et al."Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst".journal of thermal analysis and calorimetry 105.3(2011):961-968.