Rhodium(III)-Catalyzed Oxidative Coupling of 5-Aryl-1H-pyrazoles with Alkynes and Acrylates

	Rhodium(III)-Catalyzed Oxidative Coupling of 5-Aryl-1H-pyrazoles with Alkynes and Acrylates
	Li, Xingwei; Zhao, Miao
刊名	journal of organic chemistry
	2011-10-21
卷号	76 期号:20 页码:8530-8536
ISSN号	待补充
通讯作者	李兴伟
产权排序	1,1
中文摘要	rhodium(iii)-catalyzed oxidative coupling of 5-aryl-1h-pyrazoles with alkynes and acrylates
英文摘要	[rhcp*cl(2)](2)-catalyzed oxidative coupling of 5-aryl-1h-pyrazoles with alkynes and acrylates has been achieved using cu(oac)(2) as an oxidant. coupling with alkynes afforded six-membered azacycles as a result of c-c and c-n coupling. coupling with acrylates followed a process of diolefination and a subsequent aza-michael cyclization.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	h bond-cleavage ; c-h ; internal alkynes ; benzoic-acids ; derivatives ; activation ; coupling/cyclization ; olefination ; benzamides ; alkenes
收录类别	SCI ; IC
语种	英语
WOS记录号	WOS:000295816700047
公开日期	2012-07-09
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/115604]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Li, Xingwei,Zhao, Miao. Rhodium(III)-Catalyzed Oxidative Coupling of 5-Aryl-1H-pyrazoles with Alkynes and Acrylates[J]. journal of organic chemistry,2011,76(20):8530-8536.
APA	Li, Xingwei,&Zhao, Miao.(2011).Rhodium(III)-Catalyzed Oxidative Coupling of 5-Aryl-1H-pyrazoles with Alkynes and Acrylates.journal of organic chemistry,76(20),8530-8536.
MLA	Li, Xingwei,et al."Rhodium(III)-Catalyzed Oxidative Coupling of 5-Aryl-1H-pyrazoles with Alkynes and Acrylates".journal of organic chemistry 76.20(2011):8530-8536.