An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures

	An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures
	Zhang, Zehui 1,3,4; Liu, Wujun 1; Xie, Haibo 1,2; Zhao, Zongbao K.1,2
刊名	molecules
	2011-10-01
卷号	16 期号:10 页码:8463-8474
关键词	side reaction HMF ionic liquids 1-butyl-2-(5 '-methyl-2 '-furoyl)imidazole
ISSN号	1420-3049
通讯作者	谢海波 ; 赵宗保
产权排序	1,1
中文摘要	an unexpected reaction between 5-hydroxymethylfurfural and imidazolium-based ionic liquids at high temperatures
英文摘要	a new compound was detected during the production of 5-hydroxymethylfurfural (hmf) from glucose and cellulose in the ionic liquid 1-butyl-3-methylimidazolium chloride ([bmim]cl) at high temperatures. further experiments found that it was derived from the reaction of hmf with [bmim]cl. the structure of new compound was established as 1-butyl-2-(5'-methyl-2'-furoyl) imidazole (bmi) based on nuclear magnetic resonance and mass spectrometry analysis, and a possible mechanism for its formation was proposed. reactions of hmf with other imidazolium-based ionic liquids were performed to check the formation of bmi. our results provided new insights in terms of side reactions between hmf and imidazolium-based ionic liquids, which should be valuable for designing better processes for the production of furans using biomass and related materials.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	physical-properties ; solvents ; solubility ; conversion ; catalysis ; chemistry ; salts
收录类别	SCI
语种	英语
WOS记录号	WOS:000296973000024
公开日期	2012-07-09
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/115575]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China 4.S Cent Univ Nationalities, Minist Educ, Coll Chem & Mat Sci, Wuhan 430074, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Zehui,Liu, Wujun,Xie, Haibo,et al. An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures[J]. molecules,2011,16(10):8463-8474.
APA	Zhang, Zehui,Liu, Wujun,Xie, Haibo,&Zhao, Zongbao K..(2011).An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures.molecules,16(10),8463-8474.
MLA	Zhang, Zehui,et al."An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures".molecules 16.10(2011):8463-8474.