Silanized Titanium Silicate (TS-1) Molecular Sieve for Promoting the Homogeneously Catalyzed Oxidation of Cyclohexane

	Silanized Titanium Silicate (TS-1) Molecular Sieve for Promoting the Homogeneously Catalyzed Oxidation of Cyclohexane
	Wang DQ ; Zhang YB ; Xiao DH ; Yang XG
	2011
会议名称	6th international conference on environmental catalysis (6th icec)
会议日期	2010-09-12
会议地点	北京
关键词	血液相容性表面接枝聚合聚丙烯无纺布 2-丙烯酰胺基-2-甲基丙磺酸
页码	723-726
通讯作者	yang xg
中文摘要	the promoting effect of titanium silicate (ts-1) molecular sieve and silanized ts-1 (ts-1-s) on the homogeneous liquid oxidation of cyclohexane catalyzed by cobalt naphthenate (co-nap) with oxygen as oxidant was investigated. both ts-1 zeolites were efficient. promoters. the conversion of cyclohexane was 7.9% with a selectivity of 83.7% when it was catalyzed by co-nap/ts-1-s, and the reaction time was reduced to 130 min as compared to 300 min with co-nap as the catalyst. the adsorption of co-nap on ts-1-s, which transformed a. homogeneous reaction into a "quasi-heterogeneous" reaction, was the reason for the better catalytic performance.
收录类别	SCI收录期刊论文
会议录	chinese journal of catalysis
会议录出版者	science china press, 16 donghuangchenggen north st, beijing 100717, peoples r china
会议录出版地	北京
语种	中文
ISSN号	0253-9837
WOS记录号	WOS:000291508200004
内容类型	会议论文
源URL	[http://ir.ciac.jl.cn/handle/322003/47514]
专题	长春应用化学研究所_长春应用化学研究所知识产出_会议论文
推荐引用方式 GB/T 7714	Wang DQ,Zhang YB,Xiao DH,et al. Silanized Titanium Silicate (TS-1) Molecular Sieve for Promoting the Homogeneously Catalyzed Oxidation of Cyclohexane[C]. 见:6th international conference on environmental catalysis (6th icec). 北京. 2010-09-12.