CATALYTIC ACTION OF MOLYBDOVANADOPHOSPHORIC ACIDS IN DIRECT HYDROXYLATION OF BENZENE--AN EXAMINATION OF THE MECHANISM OF H(2)O(2) ACTIVATION

	CATALYTIC ACTION OF MOLYBDOVANADOPHOSPHORIC ACIDS IN DIRECT HYDROXYLATION OF BENZENE--AN EXAMINATION OF THE MECHANISM OF H(2)O(2) ACTIVATION
	Xu B ; Wu Y
刊名	acta physico-chimica sinica
	1985
卷号	1 期号:3 页码:270-280
ISSN号	1000-6818
中文摘要	the catalytic behavior of h(a+n)pmo(12-n)v(n)o(40)(abbreviated to hpa-n hereafter) + h(2)o(2) system in the direct hydroxylation of benzene is completely different from that of well known fenton reagent(fe(2+) + h(2)o(2)). the comparison experiments showed that the kinetics of the decomposition of h(2)o(5) in hpa-n system generally gave sshaped curves, which is different from that in fenton system(fig.2). the sensitivity of active species generated in the hpa-n + h(2)o(2) system toward neurone is far less than that generated in fenton system, which parallels with the response to the concentration of h(+) phenol is the only product in the hpa-n system. data obtained from the hydroxyration experiments under different conditions and kinetic studies of the decomposition of h(2)o(2) showed that, although the substituted number (n) of vanadium ion in heteropoly anion and the concentration of the catalyst had a great effect on the rate of the decomposition, they had little effect on the pro duct yield(based on h(2)o(2)).
收录类别	SCI收录期刊论文
语种	中文
公开日期	2012-06-14
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/46419]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Xu B,Wu Y. CATALYTIC ACTION OF MOLYBDOVANADOPHOSPHORIC ACIDS IN DIRECT HYDROXYLATION OF BENZENE--AN EXAMINATION OF THE MECHANISM OF H(2)O(2) ACTIVATION[J]. acta physico-chimica sinica,1985,1(3):270-280.
APA	Xu B,&Wu Y.(1985).CATALYTIC ACTION OF MOLYBDOVANADOPHOSPHORIC ACIDS IN DIRECT HYDROXYLATION OF BENZENE--AN EXAMINATION OF THE MECHANISM OF H(2)O(2) ACTIVATION.acta physico-chimica sinica,1(3),270-280.
MLA	Xu B,et al."CATALYTIC ACTION OF MOLYBDOVANADOPHOSPHORIC ACIDS IN DIRECT HYDROXYLATION OF BENZENE--AN EXAMINATION OF THE MECHANISM OF H(2)O(2) ACTIVATION".acta physico-chimica sinica 1.3(1985):270-280.