Synthesis of highly dispersed and active palladium/carbon nanofiber catalyst for formic acid electrooxidation
Qin YH ; Yue-Jiang ; Yang HH ; Zhang XS ; Zhou XG ; Niu L ; Yuan WK
刊名journal of power sources
2011
卷号196期号:10页码:4609-4612
关键词FUEL-CELLS CARBON NANOTUBES PD NANOPARTICLES ANODIC CATALYST PARTICLE-SIZE OXIDATION CITRATE PT/C REDUCTION METHANOL
ISSN号0378-7753
通讯作者zhang xs
中文摘要highly dispersed and active palladium/carbon nanofiber (pd/cnf) catalyst is synthesized by nabh(4) reduction with trisodium citrate as the stabilizing agent. the obtained pd/cnf catalyst is characterized by high resolution transmission electron microscopy (hrtem) and x-ray diffraction (xrd). the results show that the pd nanoparticles with an average particle size of ca. 3.8 nm are highly dispersed on the cnf support even with a small ratio of citrate to pd precursor, which is believed to be due to the ph adjustment of citrate stabilized colloidal pd nanoparticles. the cyclic voltammetry and chronoamperometry techniques show that the obtained pd/cnf catalyst exhibits good catalytic activity and stability for the electrooxidation of formic acid. (c) 2011 elsevier b.v. all rights reserved.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000289136800025
公开日期2012-06-11
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/44640]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Qin YH,Yue-Jiang,Yang HH,et al. Synthesis of highly dispersed and active palladium/carbon nanofiber catalyst for formic acid electrooxidation[J]. journal of power sources,2011,196(10):4609-4612.
APA Qin YH.,Yue-Jiang.,Yang HH.,Zhang XS.,Zhou XG.,...&Yuan WK.(2011).Synthesis of highly dispersed and active palladium/carbon nanofiber catalyst for formic acid electrooxidation.journal of power sources,196(10),4609-4612.
MLA Qin YH,et al."Synthesis of highly dispersed and active palladium/carbon nanofiber catalyst for formic acid electrooxidation".journal of power sources 196.10(2011):4609-4612.
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