Mesoporous SrF2 and SrF2:Ln(3+) (Ln = Ce, Tb, Yb, Er) Hierarchical Microspheres: Hydrothermal Synthesis, Growing Mechanism, and Luminescent Properties | |
Zhang CM ; Hou ZY ; Chai RT ; Cheng ZY ; Xu ZH ; Li CX ; Huang L ; Lin J | |
刊名 | journal of physical chemistry c |
2010 | |
卷号 | 114期号:15页码:6928-6936 |
关键词 | INDUCED SELF-TRANSFORMATION UP-CONVERSION LUMINESCENCE PHOTOLUMINESCENT PROPERTIES STRONTIUM FLUORIDE OPTICAL-PROPERTIES ROOM-TEMPERATURE FACILE SYNTHESIS NANOCRYSTALS NANOSTRUCTURES ARCHITECTURES |
ISSN号 | 1932-7447 |
通讯作者 | lin j |
中文摘要 | uniform and well-dispersed srf2 hierarchical microspheres have been successfully synthesized by a facile and friendly hydrothermal method. the experimental results indicate that such 3d hierarchical srf2 microspheres with size about 1 mu m are assembled by numerous nanocrystals (about 100 nm). nitrogen adsorption-desorption measurement suggests that mesopores exist in these hierarchical microarchitectures. the formation process of the hierarchical srf2 microspheres and luminescence properties of srf2:ln(3+) (ln = ce, tb, yb, er) microspheres have been investigated in detail. it is found that reaction time and trisodium citrate play a key role in forming the hierarchical microspheres. in addition, the lanthanide ions (ln(3+))-doped srf2 hierarchical microspheres show strong green (ln(3+) = ce3+, tb3+) photoluminescence with 45% quantum efficiency and cathodoluminescence centered at 542 nm corresponding to the d-5(4) -> f-7(5) transition of tb3+ under excitation of ultraviolet light and low-voltage electron beam, respectively. in addition, srf2:yb3+,er3+ hierarchical microspheres show bright yellow upconversion emission under 980 nm laser diode excitation. the as-synthesized srf2:ln(3+) luminescent microspheres might find some potential applications in areas of photoluminescence and field emission displays. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000276562500008 |
公开日期 | 2012-06-06 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43804] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang CM,Hou ZY,Chai RT,et al. Mesoporous SrF2 and SrF2:Ln(3+) (Ln = Ce, Tb, Yb, Er) Hierarchical Microspheres: Hydrothermal Synthesis, Growing Mechanism, and Luminescent Properties[J]. journal of physical chemistry c,2010,114(15):6928-6936. |
APA | Zhang CM.,Hou ZY.,Chai RT.,Cheng ZY.,Xu ZH.,...&Lin J.(2010).Mesoporous SrF2 and SrF2:Ln(3+) (Ln = Ce, Tb, Yb, Er) Hierarchical Microspheres: Hydrothermal Synthesis, Growing Mechanism, and Luminescent Properties.journal of physical chemistry c,114(15),6928-6936. |
MLA | Zhang CM,et al."Mesoporous SrF2 and SrF2:Ln(3+) (Ln = Ce, Tb, Yb, Er) Hierarchical Microspheres: Hydrothermal Synthesis, Growing Mechanism, and Luminescent Properties".journal of physical chemistry c 114.15(2010):6928-6936. |
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