Study of the ability of self-assembled N-vinylcarbazole monolayers to protect copper against corrosion | |
C. T. Wang ; S. H. Chen ; H. Y. Ma ; L. Hua ; N. X. Wang | |
刊名 | Journal of the Serbian Chemical Society |
2002 | |
卷号 | 67期号:10页码:685-696 |
关键词 | self-assembled monolayers N-vinylcarbazole copper EIS XPS alkanethiols electrodissolution mechanisms electrodes impedance behavior films gold |
ISSN号 | 0352-5139 |
中文摘要 | N-Vinylcarbazole (NVC) monolayers; were self-assembled on copper surfaces. The electrochemical properties of the copper surfaces modified by NVC self-assembled monolayers, (SAMs) were investigated using polarization and electrochemical impedance spectroscopic (EIS) methods. The polarization measurements indicated that the NVC SAMs could reduce the rates of the anodic and cathodic reaction on the surface of copper electrodes in 0.5 mol dm(-3) NaCl solution. The EIS results showed the NVC formed a closely packed film that was able to inhibit copper corrosion. X-Ray photoelectron spectroscopy (XPS) analysis of the copper samples and atomic adsorption analysis of the solution showed that the copper surfaces were covered by NVC SAMs, and the adsorption of NVC on the copper surfaces was accompanied with dissolution of Cu into the solution. |
原文出处 | |
公开日期 | 2012-04-14 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/36429] |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | C. T. Wang,S. H. Chen,H. Y. Ma,et al. Study of the ability of self-assembled N-vinylcarbazole monolayers to protect copper against corrosion[J]. Journal of the Serbian Chemical Society,2002,67(10):685-696. |
APA | C. T. Wang,S. H. Chen,H. Y. Ma,L. Hua,&N. X. Wang.(2002).Study of the ability of self-assembled N-vinylcarbazole monolayers to protect copper against corrosion.Journal of the Serbian Chemical Society,67(10),685-696. |
MLA | C. T. Wang,et al."Study of the ability of self-assembled N-vinylcarbazole monolayers to protect copper against corrosion".Journal of the Serbian Chemical Society 67.10(2002):685-696. |
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