Gyromagnetic factor of Cr4+ ions in forsterite | |
W. C. Zheng ; X. X. Wu ; Y. J. Fan | |
刊名 | Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy
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2005 | |
卷号 | 61期号:8页码:1905-1908 |
关键词 | electron paramagnetic resonance charge-transfer mechanism crystal and ligand-field theory Cr4+ Mg2SiO4 electron-paramagnetic-resonance chromium-doped forsterite atomic screening constants scf functions lasing center spectroscopy semiconductors parameters excitation cr-4+ |
ISSN号 | 1386-1425 |
中文摘要 | The average value of g factor (i.e., (g) over bar) of Cr4+ ions in forsterite (Mg2SiO4) is calculated with the cubic symmetry approximation from the complete high-order perturbation formula of g factor for 3d(2) ion in cubic tetrahedral cluster. In the formula, the contribution to g factor from the charge-transfer mechanism (which is neglected in the crystal-field theory) is considered in addition to that from the widely used crystal-field mechanism. From the calculations, the reasonable observed value of is suggested (note: the experimental values of by various authors are scattered) and the important contribution of charge-transfer mechanism to g factor can be found. (c) 2004 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/35286] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng,X. X. Wu,Y. J. Fan. Gyromagnetic factor of Cr4+ ions in forsterite[J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,2005,61(8):1905-1908. |
APA | W. C. Zheng,X. X. Wu,&Y. J. Fan.(2005).Gyromagnetic factor of Cr4+ ions in forsterite.Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,61(8),1905-1908. |
MLA | W. C. Zheng,et al."Gyromagnetic factor of Cr4+ ions in forsterite".Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 61.8(2005):1905-1908. |
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