Optical spectrum and local lattice structure for ruby | |
H. Wang ; X. Y. Kuang ; A. J. Mao ; X. F. Huang | |
刊名 | European Physical Journal B
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2007 | |
卷号 | 55期号:1页码:40913 |
关键词 | crystal fields ions absorption covalency shifts al2o3 line |
ISSN号 | 1434-6028 |
中文摘要 | By diagonalizing the 120 x 120 complete energy matrices for d(3) ion in trigonal crystal field, which contains the electrostatic interaction, the trigonal field as well as the spin-orbit interaction, the unified calculation of the whole optical and EPR spectra for ruby are made. And matrix elements of the Zeeman energy with the magnetic field parallel or perpendicular to the trigonal axis are introduced into the complete energy matrices for obtaining the g factors of the energy levels. It is concluded that zero-field splitting and optical spectra as well as g factors are in good agreement with the experimental data and the distorted local lattice structure is determined firstly results from a stretching of the O2- ions along the C-3 axis. The pressure-induced shifts of energy levels, g factors and local lattice structure are also discussed. In particular, all the calculations are carried out successfully within the framework of the crystal-field model which is consistent with the opinion of Macfarlane and Sturge that if all terms within the d(3) configuration are included, one need not go outside conventional crystal-field theory. |
原文出处 | |
公开日期 | 2012-04-13 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/33855] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. Wang,X. Y. Kuang,A. J. Mao,et al. Optical spectrum and local lattice structure for ruby[J]. European Physical Journal B,2007,55(1):40913. |
APA | H. Wang,X. Y. Kuang,A. J. Mao,&X. F. Huang.(2007).Optical spectrum and local lattice structure for ruby.European Physical Journal B,55(1),40913. |
MLA | H. Wang,et al."Optical spectrum and local lattice structure for ruby".European Physical Journal B 55.1(2007):40913. |
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