Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate | |
R. P. Chai ; X. Y. Kuang ; M. L. Duan ; C. X. Zhang | |
刊名 | Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy |
2010 | |
卷号 | 77期号:1页码:253-257 |
关键词 | EPR parameters Defect structure Complete energy matrices linbo3 single-crystals wave-guide lasers 24 degrees c superposition model local-structure ions sites spectroscopy diffraction fields |
ISSN号 | 1386-1425 |
中文摘要 | The optical and EPR spectra of octahedral Er(3+) center in LiNbO(3) have been studied by diagonalizing 364 x 364 complete energy matrices. The new set of crystal-field parameters that can well account for the Stark levels and EPR parameters have been obtained for Er(3+) ions in LiNbO(3). Simultaneously, by simulating the most reliable six-order parameter B(60) obtained, we have presented the evidence that the Er(3+) ions do not occupy the actual Li(+) site, but have a displacement along the C(3)-axis away from the Li(+) center by about 0.0454 nm. The conclusion is well in accord with that drawn by earlier workers. (c) 2010 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-13 |
内容类型 | 期刊论文 |
源URL | [http://210.72.142.130/handle/321006/31014] |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | R. P. Chai,X. Y. Kuang,M. L. Duan,et al. Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate[J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,2010,77(1):253-257. |
APA | R. P. Chai,X. Y. Kuang,M. L. Duan,&C. X. Zhang.(2010).Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate.Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,77(1),253-257. |
MLA | R. P. Chai,et al."Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate".Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 77.1(2010):253-257. |
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