Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers

	Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers
	Geng YH ; Huang L ; Wu SP ; Wang FS
刊名	science china-chemistry
	2010
卷号	53 期号:8 页码:1620-1633
关键词	CATALYST-TRANSFER POLYCONDENSATION TRANSFER CONDENSATION POLYMERIZATION CONTROLLED MOLECULAR-WEIGHT GRIGNARD METATHESIS METHOD FIELD-EFFECT TRANSISTORS REGIOREGULAR POLY(3-HEXYLTHIOPHENE) BLOCK-COPOLYMERS FACILE SYNTHESIS LOW POLYDISPERSITY DIBLOCK COPOLYMER
ISSN号	1674-7291
通讯作者	geng yh
中文摘要	kumada chain-growth polycondensation (kcgp) is a novel method for the synthesis of well-defined conjugated polymers. because the ni-catalyst can transfer in an intramolecular process to the propagating chain end, the polymerization follows chain-growth mechanism. with this newly developed method, various conjugated polymers, such as polythiophenes, poly(p-phenylene) (ppp), polypyrrole (ppy), and polyfluorene with controlled molecular weights and relatively narrow polydispersities (pdis), have been prepared. especially, the polymerizations for poly(3-alkylthiophene)s (p3ats), ppp, and ppy exhibited quasi-living characteristics, which allows preparing polymer brushes, fully-conjugated block copolymers, and macroinitiators and macro-reactants for the synthesis of rod-coil block copolymers. in the current review, the progress in this new area is summarized.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000281403400003
公开日期	2012-04-26
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/43486]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Geng YH,Huang L,Wu SP,et al. Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers[J]. science china-chemistry,2010,53(8):1620-1633.
APA	Geng YH,Huang L,Wu SP,&Wang FS.(2010).Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers.science china-chemistry,53(8),1620-1633.
MLA	Geng YH,et al."Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers".science china-chemistry 53.8(2010):1620-1633.