Switchable charge transport path via a potassium ions promoted conformational change of G-quadruplex probe monolayer | |
Zhang, J ; Wan, Y ; Wang, LH(王丽华) ; Song, SP(宋世平) ; Li, D(李迪) ; Fan, CH(樊春海) | |
刊名 | ELECTROCHEMISTRY COMMUNICATIONS |
2008 | |
卷号 | 10期号:9页码:1258 |
ISSN号 | 1388-2481 |
通讯作者 | Li, D (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China |
英文摘要 | This communication describes a potassium ions promoted switchable charge transport path via a G-quadruplex probe monolayer. Guanine-rich (G-rich) segments are known to form specific four-stranded helical conformation (G-quadruplex) in the presence of K+ via intramolecular hydrogen bonds between guanines. In the absence of K+, this G-rich oligonucleoticle is in a loosely random-coil like state and this conformational change is reversible. This conform switchable G-rich probe monolayer provide a switchable charge transport path for the oxidation of Fe(CN)(6)(4-). The K+ promoted charge transport switch were monitored by cyclic voltammetry and square-wave Voltammetry (SVW). (C) 2008 Elsevier B.V. All rights reserved. |
学科主题 | Chemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000259438200012 |
公开日期 | 2012-04-18 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/7844] |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2004-2010年 |
推荐引用方式 GB/T 7714 | Zhang, J,Wan, Y,Wang, LH,et al. Switchable charge transport path via a potassium ions promoted conformational change of G-quadruplex probe monolayer[J]. ELECTROCHEMISTRY COMMUNICATIONS,2008,10(9):1258. |
APA | Zhang, J,Wan, Y,Wang, LH,Song, SP,Li, D,&Fan, CH.(2008).Switchable charge transport path via a potassium ions promoted conformational change of G-quadruplex probe monolayer.ELECTROCHEMISTRY COMMUNICATIONS,10(9),1258. |
MLA | Zhang, J,et al."Switchable charge transport path via a potassium ions promoted conformational change of G-quadruplex probe monolayer".ELECTROCHEMISTRY COMMUNICATIONS 10.9(2008):1258. |
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