Switchable charge transport path via a potassium ions promoted conformational change of G-quadruplex probe monolayer
Zhang, J ; Wan, Y ; Wang, LH(王丽华) ; Song, SP(宋世平) ; Li, D(李迪) ; Fan, CH(樊春海)
刊名ELECTROCHEMISTRY COMMUNICATIONS
2008
卷号10期号:9页码:1258
ISSN号1388-2481
通讯作者Li, D (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
英文摘要This communication describes a potassium ions promoted switchable charge transport path via a G-quadruplex probe monolayer. Guanine-rich (G-rich) segments are known to form specific four-stranded helical conformation (G-quadruplex) in the presence of K+ via intramolecular hydrogen bonds between guanines. In the absence of K+, this G-rich oligonucleoticle is in a loosely random-coil like state and this conformational change is reversible. This conform switchable G-rich probe monolayer provide a switchable charge transport path for the oxidation of Fe(CN)(6)(4-). The K+ promoted charge transport switch were monitored by cyclic voltammetry and square-wave Voltammetry (SVW). (C) 2008 Elsevier B.V. All rights reserved.
学科主题Chemistry
收录类别SCI
语种英语
WOS记录号WOS:000259438200012
公开日期2012-04-18
内容类型期刊论文
源URL[http://ir.sinap.ac.cn/handle/331007/7844]  
专题上海应用物理研究所_中科院上海应用物理研究所2004-2010年
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GB/T 7714
Zhang, J,Wan, Y,Wang, LH,et al. Switchable charge transport path via a potassium ions promoted conformational change of G-quadruplex probe monolayer[J]. ELECTROCHEMISTRY COMMUNICATIONS,2008,10(9):1258.
APA Zhang, J,Wan, Y,Wang, LH,Song, SP,Li, D,&Fan, CH.(2008).Switchable charge transport path via a potassium ions promoted conformational change of G-quadruplex probe monolayer.ELECTROCHEMISTRY COMMUNICATIONS,10(9),1258.
MLA Zhang, J,et al."Switchable charge transport path via a potassium ions promoted conformational change of G-quadruplex probe monolayer".ELECTROCHEMISTRY COMMUNICATIONS 10.9(2008):1258.
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