In response to severe haze pollution, the Chinese State Council set PM2.5 improvement targets for the Beijing-Tianjin-Hebei (BTH) region in 2013. To achieve the targets for the residential sector, semi-coke briquettes are being considered as a replacement for traditional raw coals with the help of financial subsidy, but information on the emission from them and the impacts on the air quality is limited. Laboratory experiments were conducted to determine emission factors (EFs) for a typical semi-coke briquette, its parent material (bituminous raw-coal-chunk) and three types of traditional coals (bituminous raw-coal-chunk, anthracite raw-coal-chunk and anthracite coal-briquette) extensively used in BTH. Compared with the parent material, significant lower EFs of primary PM2.5, organic carbon (OC), element carbon (EC), the sum of 16 polycyclic aromatic hydrocarbon components (PAHs), SO42−, NO3−, hazardous trace elements (HTEs) and NOx were found in semi-coke briquette. A scenario for the BTH region in 2015 in which raw coals were replaced with the semi-coke briquette showed that amounts of pollutants emitted from residential coal combustion could decrease by 91.6% for primary PM2.5, 94.0% for OC, 99.6% for EC, 99.9% for PAHs, 94.2% for NO3−, 45.6% for HTEs, 70.9% for NOx and 22.3% for SO2. However, SO42− loadings evidently would increase if raw coals were replaced with either semi-coke briquette or anthracite coal-briquette. Geographic distributions of modeled reductions were developed to identify emission-reducing hot-spots and aid in the development of clean energy policies. Replacement of traditional raw coals with the semi-coke briquette apparently could lead to significant environmental improvements in BTH and other regions in China.