Spectroscopy of High-Energy States of Lanthanide Ions

doi:10.1002/ejic.201000182

	Spectroscopy of High-Energy States of Lanthanide Ions
	Reid, Michael F.1; Hu, Liusen 1,2; Frank, Sebastian 1; Duan, Chang-Kui 3; Xia, Shangda 2; Yin, Min 2
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2010-06-01
页码	2649-2654
关键词	Lanthanides Rare earths Crystal field Ab initio calculations UV/Vis spectroscopy Laser spectroscopy
ISSN号	1434-1948
DOI	10.1002/ejic.201000182
英文摘要	We discuss recent progress and future prospects for the analysis of the 4f(N-1)5d excited states of lanthanide ions in host materials. We demonstrate how ab initio calculations for Ce(3+) in LiYF(4) may be used to estimate crystal-field and spin-orbit parameters for the 4f(1) and 5d(1) configurations. We show how excited-state absorption may be used to probe the electronic and geometric structure of the 4f(N-1)5d excited states in more detail and we illustrate the possibilities with calculations for Yb(2+) ions in SrCl(2).
资助项目	International Conference on f-Elements ; Chinese Government ; National Natural Science Foundation of China[10874173] ; National Natural Science Foundation of China[10874253]
WOS关键词	RARE-EARTH IONS ; AB-INITIO CALCULATION ; CRYSTAL-FIELD ; TRIVALENT LANTHANIDES ; INORGANIC-COMPOUNDS ; CUBIC CRYSTALS ; LIYF4 CRYSTAL ; SIMPLE-MODEL ; SPECTRA ; ABSORPTION
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000279975400013
资助机构	International Conference on f-Elements ; Chinese Government ; National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://119.78.100.186/handle/113462/31693]
专题	中国科学院近代物理研究所
通讯作者	Reid, Michael F.
作者单位	1.Univ Canterbury, Inst Adv Mat & Nanotechnol, Dept Phys & Astron & MacDiarmid, Christchurch 1, New Zealand 2.Univ Sci & Technol China, Dept Phys, Hefei 230026, Peoples R China 3.Chongqing Univ Post & Telecommun, Inst Modern Phys, Chongqing 400065, Peoples R China
推荐引用方式 GB/T 7714	Reid, Michael F.,Hu, Liusen,Frank, Sebastian,et al. Spectroscopy of High-Energy States of Lanthanide Ions[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2010:2649-2654.
APA	Reid, Michael F.,Hu, Liusen,Frank, Sebastian,Duan, Chang-Kui,Xia, Shangda,&Yin, Min.(2010).Spectroscopy of High-Energy States of Lanthanide Ions.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2649-2654.
MLA	Reid, Michael F.,et al."Spectroscopy of High-Energy States of Lanthanide Ions".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2010):2649-2654.