Chemical Phase Analysis of Rare Earth Elements in Cobalt-rich Crusts and Its Application | |
Gao Jing-Jing1,2; Liu Ji-Hua2; Li Xian-Guo1; Zhang Hui2; He Lian-Hua2 | |
刊名 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
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2015-12 | |
卷号 | 43期号:12页码:1895-1900 |
关键词 | Cobalt-rich crusts Rare earth elements Chemical phase Selective chemical extraction method |
ISSN号 | 0253-3820 |
英文摘要 | Selective chemical extraction method was utilized to fractionally extract rare earth elements (REEs) in cobalt. rich crusts and bedrock samples from the Pacific survey area, and REEs concentrations were determined by inductively coupled plasma mass spectrometry (ICP-MS). A method was established for the chemical phases analysis of REEs in cobalt. rich crusts. The results showed that the REEs enrichment in different phases in cobalt. rich crusts conformed to the following order: iron oxide phase>manganese oxide phase>residual phase>carbonate phase>adsorbed phase. About 70.2%-73.9% of total REEs contents were mainly enriched in the iron oxide phase and the recoveries were 94.8%-105.9%. Therefore, most of REEs were controlled by amorphous FeOOH minerals. In different geological bodies, occurrence phase of REEs had significant difference. REEs were mainly enriched in the carbonate phase in carbonate rock, the residual phase in basalt and phosphate rock, and the iron oxide phase in cobalt. rich crusts and polymetallic nodules. In different structural layer of cobalt. rich crusts, REEs in the new layer were mainly enriched in the iron oxide phase, and REEs in the old layer were mainly enriched in the residual phase. It suggested that phospharization played a more significant role on the REEs enrichment in the old layer. |
WOS研究方向 | Chemistry |
语种 | 中文 |
出版者 | ELSEVIER SCIENCE INC |
WOS记录号 | WOS:000371689300012 |
内容类型 | 期刊论文 |
源URL | [http://ir.fio.com.cn/handle/2SI8HI0U/3571] ![]() |
专题 | 业务部门_海洋地质与地球物理研究室 |
作者单位 | 1.Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China; 2.State Ocean Adm, Inst Oceanog 1, Key Lab Marine Sedimentary & Environm Geol, Qingdao 266061, Peoples R China |
推荐引用方式 GB/T 7714 | Gao Jing-Jing,Liu Ji-Hua,Li Xian-Guo,et al. Chemical Phase Analysis of Rare Earth Elements in Cobalt-rich Crusts and Its Application[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2015,43(12):1895-1900. |
APA | Gao Jing-Jing,Liu Ji-Hua,Li Xian-Guo,Zhang Hui,&He Lian-Hua.(2015).Chemical Phase Analysis of Rare Earth Elements in Cobalt-rich Crusts and Its Application.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,43(12),1895-1900. |
MLA | Gao Jing-Jing,et al."Chemical Phase Analysis of Rare Earth Elements in Cobalt-rich Crusts and Its Application".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 43.12(2015):1895-1900. |
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