A charged metal-organic framework for CO2/CH4 and CO2/N-2 separation

doi:10.1016/j.ica.2016.01.014

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	A charged metal-organic framework for CO2/CH4 and CO2/N-2 separation
	Zhong, Ruiqin ; Xu, Zhilong ; Bi, Wenzhu ; Han, Songbai ; Yu, Xiaofeng ; Zou, Ruqiang
刊名	INORGANICA CHIMICA ACTA
	2016
关键词	Metal-organic framework CO2 separation Gas adsorption Selectivity POROUS COORDINATION POLYMER CARBON-DIOXIDE CAPTURE CO2 CAPTURE MOLECULAR SIMULATION MAGNETIC-PROPERTIES SWING ADSORPTION SELECTIVITY MOFS STORAGE BINDING
DOI	10.1016/j.ica.2016.01.014
英文摘要	A microporous metal-organic framework [InL][(CH3)(2)NH2]center dot(H4L = 9-(3,5-dicarboxyphenyl)carbazole-3,6-dicarboxylic acid) (1) was hydrothermally synthesized and structurally characterized by single crystal Xray diffraction and powder X-ray diffraction. The adsorption behavior of 1 has been investigated with respect to CO2, CH4 and N-2, and the separation efficiency has been calculated by the Henry's law analysis of isotherm data. The results indicated that the anionic framework with the inside protonated dimethylamine could enhance its selective adsorption performance for CO2 through strong adsorbent-adsorbate interaction aroused by a strong electrostatic field and pore size effect. (C) 2016 Elsevier B.V. All rights reserved.; National Natural Science Foundation of China (NSFC) [21203249, 11375271]; Science Foundation of China University of Petroleum, Beijing [01JB0229]; SCI(E); ARTICLE; 299-303; 443
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/438421]
专题	工学院
推荐引用方式 GB/T 7714	Zhong, Ruiqin,Xu, Zhilong,Bi, Wenzhu,et al. A charged metal-organic framework for CO2/CH4 and CO2/N-2 separation[J]. INORGANICA CHIMICA ACTA,2016.
APA	Zhong, Ruiqin,Xu, Zhilong,Bi, Wenzhu,Han, Songbai,Yu, Xiaofeng,&Zou, Ruqiang.(2016).A charged metal-organic framework for CO2/CH4 and CO2/N-2 separation.INORGANICA CHIMICA ACTA.
MLA	Zhong, Ruiqin,et al."A charged metal-organic framework for CO2/CH4 and CO2/N-2 separation".INORGANICA CHIMICA ACTA (2016).