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In situ fast polymerization of graphene nanosheets-filled poly(methyl methacrylate) nanocomposites
Zhang, Lan-Ying ; Zhang, Yang-Fei
刊名JOURNAL OF APPLIED POLYMER SCIENCE
2016
关键词composites graphene and fullerenes microscopy nanotubes properties and characterization MECHANICAL-PROPERTIES ELECTRICAL-CONDUCTIVITY FUNCTIONALIZED GRAPHENE BULK-POLYMERIZATION COMPOSITES SHEETS OXIDE PMMA DISPERSION REDUCTION
DOI10.1002/app.43423
英文摘要A series of graphene nanosheets-filled poly(methyl methacrylate) nanocomposites (GNS/PMMA) is successfully prepared by an in situ fast polymerization method with graphene weight fractions from 0.1 to 2.0 wt %. In situ polymerization is effective in well dispersing of GNS in matrixes and suitable for both low and high content of GNS. The synthesis processes of polymer composites could be simplified and fast by using industrial grade graphene. The GNS fillers are found to disperse homogeneously in the PMMA matrix. The maximum electrical conductivity of the composites achieves 0.57 Sm-1, with an extremely low percolation threshold of 0.3 wt %. The electrical conductivities are further predicted by percolation theory and found to agree well with the experimental results. The results indicate that the microstructures, thermal, electrical, and mechanical properties of PMMA polymer are significantly improved by adding a low amount of graphene nanosheets. (c) 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43423.; National Natural Science Foundation of China [11202005, 51203003, 51573003]; Beijing Natural Science Foundation [3122019]; SCI(E); EI; ARTICLE; zhangyangfei@pku.edu.cn; 19; 133
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/437256]  
专题工学院
推荐引用方式
GB/T 7714
Zhang, Lan-Ying,Zhang, Yang-Fei. In situ fast polymerization of graphene nanosheets-filled poly(methyl methacrylate) nanocomposites[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2016.
APA Zhang, Lan-Ying,&Zhang, Yang-Fei.(2016).In situ fast polymerization of graphene nanosheets-filled poly(methyl methacrylate) nanocomposites.JOURNAL OF APPLIED POLYMER SCIENCE.
MLA Zhang, Lan-Ying,et al."In situ fast polymerization of graphene nanosheets-filled poly(methyl methacrylate) nanocomposites".JOURNAL OF APPLIED POLYMER SCIENCE (2016).
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