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Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model
Ge, Xinlei ; Wang, Xidong
刊名journal of solution chemistry
2009
关键词Electrolyte solutions Freezing point Boiling point Enthalpy of vaporization SATURATED AQUEOUS-SOLUTIONS CHEMICAL-EQUILIBRIUM MODEL LOCAL COMPOSITION MODEL EXCESS GIBBS ENERGY MODIFIED TCPC MODEL THERMODYNAMIC PROPERTIES OSMOTIC COEFFICIENTS LITHIUM-CHLORIDE MOLAR ENTHALPIES SODIUM-CHLORIDE
DOI10.1007/s10953-009-9433-0
英文摘要A method was proposed for calculating the thermodynamic properties, freezing point depression, boiling point elevation, vapor pressure and enthalpy of vaporization for single solute electrolyte solutions, including aqueous and nonaqueous solutions, based on a modified three-characteristic-parameter correlation model. When compared with the corresponding literature values, the calculated results show that this method gives a very good approximation, especially for 1-1 electrolytes. Although the method is not very suitable for some solutions with very high ionic strength, it is still a very useful technique when experimental data is scarce.; Chemistry, Physical; SCI(E); 4; ARTICLE; 9; 1097-1117; 38
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/247574]  
专题工学院
推荐引用方式
GB/T 7714
Ge, Xinlei,Wang, Xidong. Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model[J]. journal of solution chemistry,2009.
APA Ge, Xinlei,&Wang, Xidong.(2009).Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model.journal of solution chemistry.
MLA Ge, Xinlei,et al."Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model".journal of solution chemistry (2009).
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