Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model | |
Ge, Xinlei ; Wang, Xidong | |
刊名 | journal of solution chemistry |
2009 | |
关键词 | Electrolyte solutions Freezing point Boiling point Enthalpy of vaporization SATURATED AQUEOUS-SOLUTIONS CHEMICAL-EQUILIBRIUM MODEL LOCAL COMPOSITION MODEL EXCESS GIBBS ENERGY MODIFIED TCPC MODEL THERMODYNAMIC PROPERTIES OSMOTIC COEFFICIENTS LITHIUM-CHLORIDE MOLAR ENTHALPIES SODIUM-CHLORIDE |
DOI | 10.1007/s10953-009-9433-0 |
英文摘要 | A method was proposed for calculating the thermodynamic properties, freezing point depression, boiling point elevation, vapor pressure and enthalpy of vaporization for single solute electrolyte solutions, including aqueous and nonaqueous solutions, based on a modified three-characteristic-parameter correlation model. When compared with the corresponding literature values, the calculated results show that this method gives a very good approximation, especially for 1-1 electrolytes. Although the method is not very suitable for some solutions with very high ionic strength, it is still a very useful technique when experimental data is scarce.; Chemistry, Physical; SCI(E); 4; ARTICLE; 9; 1097-1117; 38 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/247574] |
专题 | 工学院 |
推荐引用方式 GB/T 7714 | Ge, Xinlei,Wang, Xidong. Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model[J]. journal of solution chemistry,2009. |
APA | Ge, Xinlei,&Wang, Xidong.(2009).Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model.journal of solution chemistry. |
MLA | Ge, Xinlei,et al."Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model".journal of solution chemistry (2009). |
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