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Simultaneous reduction of vanadium (V) and chromium (VI) with enhanced energy recovery based on microbial fuel cell technology
Zhang, Baogang ; Feng, Chuanping ; Ni, Jinren ; Zhang, Jing ; Huang, Wenli
刊名电源杂志
2012
关键词Microbial fuel cells Vanadium (V) Chromium (VI) Wastewater treatment Electricity generation AIR-CATHODE WASTE-WATER GENERATION
DOI10.1016/j.jpowsour.2012.01.013
英文摘要Vanadium (V) and chromium (VI) are the main metals found in vanadium containing wastewater with large amount and great toxicity. In present study, reduction of V(V) and Cr(VI) together with electricity generation is successfully achieved in double chamber microbial fuel cells (MFCs) by employing vanadium containing wastewater as the cathodic electron acceptor. The V(v) and Cr(VI) reduction efficiencies for 240 h operation approach up to 67.9 +/- 3.1% and 75.4 +/- 1.9%, respectively, with a maximum power density of 970.2 +/- 20.6 mW m(-2). The power output is enhanced, compared with the results from MFCs with V(V) as the sole electron acceptor, while the decrease of the cathode efficiency caused by deposits from Cr(vi) reduction process can also be mitigated. After reduction, chromium is mainly deposited on the cathode surface in the form of Cr(III), while most of vanadium can be precipitated from the exhausted catholyte by adjusting pH, thus treating vanadium containing wastewater successfully with energy harvest based on MFC technology. The operating principles of MFCs with two different electron acceptors are also reported for the first time. (C) 2012 Elsevier B.V. All rights reserved.; Electrochemistry; Energy & Fuels; SCI(E); EI; 18; ARTICLE; 34-39; 204
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/235600]  
专题环境科学与工程学院
推荐引用方式
GB/T 7714
Zhang, Baogang,Feng, Chuanping,Ni, Jinren,et al. Simultaneous reduction of vanadium (V) and chromium (VI) with enhanced energy recovery based on microbial fuel cell technology[J]. 电源杂志,2012.
APA Zhang, Baogang,Feng, Chuanping,Ni, Jinren,Zhang, Jing,&Huang, Wenli.(2012).Simultaneous reduction of vanadium (V) and chromium (VI) with enhanced energy recovery based on microbial fuel cell technology.电源杂志.
MLA Zhang, Baogang,et al."Simultaneous reduction of vanadium (V) and chromium (VI) with enhanced energy recovery based on microbial fuel cell technology".电源杂志 (2012).
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