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Pressure-induced phase transition of B-type Y2O3
Zhang, Qian ; Wu, Xiang ; Qin, Shan
刊名CHINESE PHYSICS B
2017
关键词Y2O3 x-ray diffraction pressure-induced phase transition equation of state RARE-EARTH SESQUIOXIDES AB-INITIO DIFFRACTION OXIDES
DOI10.1088/1674-1056/26/9/090703
英文摘要The synthesized monoclinic (B-type) phase of Y2O3 has been investigated by in situ angle-dispersive x-ray diffraction in a diamond anvil cell up to 44 GPa at room temperature. A phase transition occurs from monoclinic (B-type) to hexagonal (A-type) phase at 23.5 GPa and these two phases coexist even at the highest pressure. Parameters of isothermal equation of state are V-0 = 69.0 (1) angstrom(3), K-0 = 159 (3) GPa, K'(0) = 4 (fixed) for the B-type phase and V-0 = 67.8(2) angstrom(3), K-0 = 156 (3) GPa, K'(0) = 4 (fixed) for the A-type phase. The structural anisotropy increases with increasing pressure for both phases.; National Science Foundation-Earth Sciences [EAR-1128799]; Department of Energy Geosciences [DE-FG02-94ER14466]; DOE-BES [DE-AC02-06CH11357]; SCI(E); ARTICLE; 9; 26
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/471123]  
专题地球与空间科学学院
推荐引用方式
GB/T 7714
Zhang, Qian,Wu, Xiang,Qin, Shan. Pressure-induced phase transition of B-type Y2O3[J]. CHINESE PHYSICS B,2017.
APA Zhang, Qian,Wu, Xiang,&Qin, Shan.(2017).Pressure-induced phase transition of B-type Y2O3.CHINESE PHYSICS B.
MLA Zhang, Qian,et al."Pressure-induced phase transition of B-type Y2O3".CHINESE PHYSICS B (2017).
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