One-carbon homologation of arylboronic acids: a convenient approach to   the synthesis of pinacol benzylboronates

doi:10.1039/c6qo00141f

CORC > 北京大学 > 化学与分子工程学院

	One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates
	Wu, Chaoqiang ; Wu, Guojiao ; Zhang, Yan ; Wang, Jianbo
刊名	ORGANIC CHEMISTRY FRONTIERS
	2016
关键词	IRIDIUM-CATALYZED BORYLATION CROSS-COUPLING REACTIONS C-H BONDS BENZYL HALIDES ALKENYLBORONIC ACIDS ALKYLBORON COMPOUNDS ESTERS METAL ORGANOBORANES BIS(PINACOLATO)DIBORON
DOI	10.1039/c6qo00141f
英文摘要	A transition-metal-free method for the synthesis of benzylic boronate esters with arylboronic acids and trimethylsilyldiazomethane (TMSCHN2) has been developed. This transformation is a straightforward homologation of arylboronic acids, which represents a unique approach toward the preparation of pinacol benzylboronates. The reaction has a wide substrate scope and good functional-group tolerance, and it can be scaled up easily.; 973 Program [2012CB821600]; National Nature Science Foundation of China [21272010, 21332002]; SCI(E); ARTICLE; wangjb@pku.edu.cn; 7; 817-822; 3
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/492441]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wu, Chaoqiang,Wu, Guojiao,Zhang, Yan,et al. One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates[J]. ORGANIC CHEMISTRY FRONTIERS,2016.
APA	Wu, Chaoqiang,Wu, Guojiao,Zhang, Yan,&Wang, Jianbo.(2016).One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates.ORGANIC CHEMISTRY FRONTIERS.
MLA	Wu, Chaoqiang,et al."One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates".ORGANIC CHEMISTRY FRONTIERS (2016).