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Grape-Like Fe3O4 Agglomerates Grown on Graphene Nanosheets for Ultrafast and Stable Lithium Storage
Qi, Liya ; Xin, Yuelong ; Zuo, Zicheng ; Yang, Chengkai ; Wu, Kai ; Wu, Bin ; Zhou, Henghui
刊名ACS APPLIED MATERIALS & INTERFACES
2016
关键词metal oxides metal organic frameworks hybrid nanomaterials microstructures anode METAL-ORGANIC-FRAMEWORKS SODIUM-ION BATTERIES ANODE MATERIALS HOLLOW MICROSPHERES ENERGY-STORAGE BINDER-FREE PERFORMANCE COMPOSITES OXIDE NANOCOMPOSITE
DOI10.1021/acsami.6b04274
英文摘要An in situ simple and effective synthesis method is effectively exploited to construct MOF-derived grape-like architecture anchoring on nitrogen-doped graphene, in which ultrafine Fe3O4 nanoparticles are uniformly dispersed (Fe3O4@C/NG). In this hybrid hierarchical structure, new synergistic features are accessed. The graphene oxide plane with functional groups is expected to alleviate the aggregation problem in the MOFs' growth. Moreover, the morphology and size of iron-based MOFs and carbon content are conveniently controlled by controlling the solution concentration of precursor. Through making use of in situ carbonization of the organic ligands in MOFs, Fe3O4 subunits are effectively protected by 3D interconnected conductive carbon at microscale. Consequently, when applied as anode materials, even as high as 10 A g(-1) after 1000 cycles, Fe3O4@C/NG still maintains as high as 458 mA h g(-1).; A* Star Singapore China Joint Research program [2012DFG52130]; financial Technology Innovation Project of New Energy Vehicles Industry; Pulead Technology Industry Co. Ltd; SCI(E); EI; PubMed; ARTICLE; hhzhou@pku.edu.cn; 27; 17245-17252; 8
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/491894]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Qi, Liya,Xin, Yuelong,Zuo, Zicheng,et al. Grape-Like Fe3O4 Agglomerates Grown on Graphene Nanosheets for Ultrafast and Stable Lithium Storage[J]. ACS APPLIED MATERIALS & INTERFACES,2016.
APA Qi, Liya.,Xin, Yuelong.,Zuo, Zicheng.,Yang, Chengkai.,Wu, Kai.,...&Zhou, Henghui.(2016).Grape-Like Fe3O4 Agglomerates Grown on Graphene Nanosheets for Ultrafast and Stable Lithium Storage.ACS APPLIED MATERIALS & INTERFACES.
MLA Qi, Liya,et al."Grape-Like Fe3O4 Agglomerates Grown on Graphene Nanosheets for Ultrafast and Stable Lithium Storage".ACS APPLIED MATERIALS & INTERFACES (2016).
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