Colour tuning via crystalline site-selected energy transfer in a Sr2SiO4:Eu2+,Pr3+ phosphor | |
Li, Ye ; Wang, Jing ; Wang, Xiao-Ming ; Pan, Fengjuan ; Zhou, Tianliang ; Xie, Rong-Jun | |
刊名 | JOURNAL OF MATERIALS CHEMISTRY C |
2017 | |
关键词 | LIGHT-EMITTING-DIODES PHOTOLUMINESCENCE PROPERTIES SPECTRAL CONVERTERS PR3+ PHOSPHOR NIR EMISSION REFINEMENT GLASSES CE3+ MN4+ |
DOI | 10.1039/c6tc04385b |
英文摘要 | Spectral adjustment based on the energy transfer process between donor-acceptor pairs has been routinely used to design luminescent materials with different colours and absorption bandwidths. This work reports an alternative way to design new luminescent materials based on a site-selected energy transfer mechanism using high precision control of dopants. The new material Sr2SiO4: Eu2+, Pr3+ has been successfully synthesized to show versatile emissions under site-selected excitation. We demonstrate an efficient site-selected energy transfer process from Eu2+ to Pr3+ and that dual-mode spectral control can be achieved by choosing Eu2+ in Sr2SiO4 as a yellow emission centre and Pr3+ as a red and near infrared emission centre. Therefore a yellow-to-orange phosphor has been realized with excitation-dependent adjustable red and near infrared emissions. The site-selected spectral adjustments and energy transfer mechanism are investigated in detail. This work suggests the design and synthesis of new materials for application in solar cells and white LED devices.; "973'' program [2014CB643801]; National Natural Science Foundation of China [21271191, 20971130, 51272259, 51572232, 51561135015, 51602271]; SCI(E); ARTICLE; 5; 1022-1026; 5 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/476284] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li, Ye,Wang, Jing,Wang, Xiao-Ming,et al. Colour tuning via crystalline site-selected energy transfer in a Sr2SiO4:Eu2+,Pr3+ phosphor[J]. JOURNAL OF MATERIALS CHEMISTRY C,2017. |
APA | Li, Ye,Wang, Jing,Wang, Xiao-Ming,Pan, Fengjuan,Zhou, Tianliang,&Xie, Rong-Jun.(2017).Colour tuning via crystalline site-selected energy transfer in a Sr2SiO4:Eu2+,Pr3+ phosphor.JOURNAL OF MATERIALS CHEMISTRY C. |
MLA | Li, Ye,et al."Colour tuning via crystalline site-selected energy transfer in a Sr2SiO4:Eu2+,Pr3+ phosphor".JOURNAL OF MATERIALS CHEMISTRY C (2017). |
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