Steering On-Surface Reactions by a Self-Assembly Approach

doi:10.1002/anie.201700745

CORC > 北京大学 > 化学与分子工程学院

	Steering On-Surface Reactions by a Self-Assembly Approach
	Chen, Qiwei ; Cramer, Jacob R. ; Liu, Jing ; Jin, Xin ; Liao, Peilin ; Shao, Xiang ; Gothelf, Kurt V. ; Wu, Kai
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017
关键词	density functional theory dehydrocyclization on-surface reaction scanning tunneling microscope self-assembly TERMINAL ALKYNES METAL-SURFACES MOLECULAR WIRES AU(111) SURFACE NOBLE-METAL COVALENT POLYMERIZATION NANOSTRUCTURES POLYPHENYLENE
DOI	10.1002/anie.201700745
英文摘要	4,4'-Bis(2,6-difluoropyridin-4-yl)-1,1':4',1 ''-terphenyl (BDFPTP) molecules underwent dehydrocyclization and covalent coupling reactions on Au(111) according to scanning tunneling microscopy (STM) measurements and density functional theory (DFT) calculations. Self-assembly of the reactants in well-defined molecular domains prior to reaction could greatly enhance the regioselectivity of the dehydrocyclization reaction and suppress defluorinated coupling, demonstrating that self-assembly can efficiently steer on-surface reactions. Such a strategy could be of great importance in surface chemistry and widely applied to control on-surface reactions.; NSFC, China [91527303, 21333001, 21261130090]; Thousand Talent Program for Young Outstanding Scientists of the Chinese government; SCI(E); ARTICLE; 18; 5026-5030; 56
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/473902]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Chen, Qiwei,Cramer, Jacob R.,Liu, Jing,et al. Steering On-Surface Reactions by a Self-Assembly Approach[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017.
APA	Chen, Qiwei.,Cramer, Jacob R..,Liu, Jing.,Jin, Xin.,Liao, Peilin.,...&Wu, Kai.(2017).Steering On-Surface Reactions by a Self-Assembly Approach.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Chen, Qiwei,et al."Steering On-Surface Reactions by a Self-Assembly Approach".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017).