An organic-inorganic perovskite ferroelectric with large piezoelectric response (vol 357, pg 306, 2017) | |
You, Yu-Meng ; Liao, Wei-Qiang ; Zhao, Dewei ; Ye, Heng-Yun ; Zhang, Yi ; Zhou, Qionghua ; Niu, Xianghong ; Wang, Jinlan ; Li, Peng-Fei ; Fu, Da-Wei ; Wang, Zheming ; Gao, Song ; Yang, Kunlun ; Liu, Jun-Ming ; Li, Jiangyu ; Yan, Yanfa ; Xiong, Ren-Gen | |
刊名 | SCIENCE |
2017 | |
关键词 | ROOM-TEMPERATURE FERROELECTRICITY LEAD-FREE PIEZOCERAMICS DIISOPROPYLAMMONIUM BROMIDE CHARGE-TRANSFER TITANATE CERAMICS CRYSTALS |
DOI | 10.1126/science.aai8535 |
英文摘要 | Molecular piezoelectrics are highly desirable for their easy and environment-friendly processing, light weight, low processing temperature, and mechanical flexibility. However, although 136 years have passed since the discovery in 1880 of the piezoelectric effect, molecular piezoelectrics with a piezoelectric coefficient d(33) comparable with piezoceramics such as barium titanate (BTO; similar to 190 picocoulombs per newton) have not been found. We show that trimethylchloromethyl ammonium trichloromanganese(II), an organic-inorganic perovskite ferroelectric crystal processed from aqueous solution, has a large d(33) of 185 picocoulombs per newton and a high phase-transition temperature of 406 kelvin (K) (16 K above that of BTO). This makes it a competitive candidate for medical, micromechanical, and biomechanical applications.; 973 project [2014CB932103]; National Natural Science Foundation of China [21290172, 91422301, 21427801, 21290170]; National Key Research Program of China [2016YF0300101, 2016YFA0201001]; SCI(E); ARTICLE; 6348; 357 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/472051] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | You, Yu-Meng,Liao, Wei-Qiang,Zhao, Dewei,et al. An organic-inorganic perovskite ferroelectric with large piezoelectric response (vol 357, pg 306, 2017)[J]. SCIENCE,2017. |
APA | You, Yu-Meng.,Liao, Wei-Qiang.,Zhao, Dewei.,Ye, Heng-Yun.,Zhang, Yi.,...&Xiong, Ren-Gen.(2017).An organic-inorganic perovskite ferroelectric with large piezoelectric response (vol 357, pg 306, 2017).SCIENCE. |
MLA | You, Yu-Meng,et al."An organic-inorganic perovskite ferroelectric with large piezoelectric response (vol 357, pg 306, 2017)".SCIENCE (2017). |
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