Efficient Modular Synthesis of Substituted Borazaronaphthalene

doi:10.1021/acs.organomet.6b00811

CORC > 北京大学 > 化学与分子工程学院

	Efficient Modular Synthesis of Substituted Borazaronaphthalene
	Zhuang, Fang-Dong ; Han, Ji-Min ; Tang, Sheng ; Yang, Jing-Hui ; Chen, Qi-Ran ; Wang, Jie-Yu ; Pei, Jian
刊名	ORGANOMETALLICS
	2017
关键词	FIELD-EFFECT TRANSISTORS 25TH ANNIVERSARY ARTICLE BROMINATED 2,1-BORAZARONAPHTHALENES HETEROAROMATIC COMPOUNDS CONJUGATED POLYMERS 1,1-HYDROBORATION SEMICONDUCTOR PERFORMANCE BORYLATION STABILITY
DOI	10.1021/acs.organomet.6b00811
英文摘要	A highly efficient modular synthetic method for BN-fused polycyclic aromatic hydrocarbons (PAHs) composed of a borazaronaphthalene core along with multiple functionalized sites is reported. The halogenated 2,1-borazaronaphthalene cores are constructed through a ring-closing reaction between o-ethynylaniline derivatives and boron halides. The controllable halogen substituents make further derivatization of 2,1-borazaronaphthalene cores feasible by using metal-catalyzed cross-coupling reactions. On the basis of the carefully designed precursors, various functional aromatic rings can be fused to the azaborine core via a one-pot nucleophilic tandem reaction, affording previously inaccessible PAHs in moderate yields.; Major State Basic Research Development Program from the Ministry of Science and Technology [2013CB933501, 2015CB856505]; National Natural Science Foundation of China [21302009, 21190031, 51273003, 91427303, 21420102005]; SCI(E); ARTICLE; 14; 2479-2482; 36
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/472033]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhuang, Fang-Dong,Han, Ji-Min,Tang, Sheng,et al. Efficient Modular Synthesis of Substituted Borazaronaphthalene[J]. ORGANOMETALLICS,2017.
APA	Zhuang, Fang-Dong.,Han, Ji-Min.,Tang, Sheng.,Yang, Jing-Hui.,Chen, Qi-Ran.,...&Pei, Jian.(2017).Efficient Modular Synthesis of Substituted Borazaronaphthalene.ORGANOMETALLICS.
MLA	Zhuang, Fang-Dong,et al."Efficient Modular Synthesis of Substituted Borazaronaphthalene".ORGANOMETALLICS (2017).