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	Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling
	Bai, Shi-Qiang ; Jiang, Lu ; Zuo, Jing-Lin ; Yan, Chun-Hua ; Hor, T. S. Andy
	2013
英文摘要	A new dinuclear Cu(ii) complex [Cu2Cl4(L1) 2] (1) (L1&le1-(2-picolyl)-4-hexyl-1H-1,2,3-triazole) has been synthesised and characterised by single-crystal X-ray diffraction (XRD) and powder XRD, thermogravimetric analysis, electron paramagnetic resonance spectrum, photoluminescence, and magnetic measurements. Complex 1 shows double 1,2,3-triazoles bridging the dinuclear Cu2N4 moiety, in which the bridging N&leN bond indicates basal-apical asymmetric mode with 112.6?? torsion angle of Cu-N&leN-Cu. Different from most azole-bridged dinuclear Cu(ii) with antiferromagnetic couplings, complex 1 shows an intramolecular weak ferromagnetic interaction (J&le0.91cm-1). ? 2013 CSIRO.; EI; 9; 1029-1033; 66
语种	英语
DOI标识	10.1071/CH13224
内容类型	其他
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/461357]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Bai, Shi-Qiang,Jiang, Lu,Zuo, Jing-Lin,et al. Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling. 2013-01-01.

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