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Investigation on the intermolecular interaction between diethyl ether and dichloromethane in gaseous phase by using the DAOSD approach
Chen, Mo ; Guo, Ran ; Zhao, Ying ; Weng, Shifu ; Xu, Yizhuang ; Noda, Isao ; Wu, Jinguang
2016
关键词2D correlation spectra Gas FT-IR spectroscopy DAOSD Intermolecular interaction SAMPLE DESIGN SCHEME 2-DIMENSIONAL SYNCHRONOUS SPECTROSCOPY INFRARED CORRELATION SPECTROSCOPY DIPOLE-DIPOLE INTERACTIONS ASYNCHRONOUS SPECTROSCOPY CROSS PEAKS CONCENTRATION SERIES SOLUTION MIXTURES ORGANIC-LIGANDS IR SPECTROSCOPY
英文摘要Intermolecular interaction between diethyl ether and dichloromethane was investigated by using double asynchronous orthogonal sample design (DAOSD) scheme. FT-IR spectra of the two compounds were measured in the gas phase. A gas cell that satisfied the requirement of the DAOSD approach was designed, fabricated and utilized. The appearance of cross peaks in a pair of asynchronous spectra demonstrated that intermolecular interaction occurred between two compounds. Interference from the spectra of solvent can be avoided by measuring the samples in gas phase, thereby extending the application range of DAOSD and relevant approaches. (C) 2015 Elsevier B.V. All rights reserved.; SCI(E); CPCI-S(ISTP); xyz@pku.edu.cn; ,SI; 244-248; 1124
语种英语
出处8th International Symposium on Two-Dimensional Correlation Spectroscopy (2DCOS)
DOI标识10.1016/j.molstruc.2015.12.015
内容类型其他
源URL[http://ir.pku.edu.cn/handle/20.500.11897/456887]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Chen, Mo,Guo, Ran,Zhao, Ying,et al. Investigation on the intermolecular interaction between diethyl ether and dichloromethane in gaseous phase by using the DAOSD approach. 2016-01-01.
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