Investigation on the intermolecular interaction between diethyl ether and dichloromethane in gaseous phase by using the DAOSD approach | |
Chen, Mo ; Guo, Ran ; Zhao, Ying ; Weng, Shifu ; Xu, Yizhuang ; Noda, Isao ; Wu, Jinguang | |
2016 | |
关键词 | 2D correlation spectra Gas FT-IR spectroscopy DAOSD Intermolecular interaction SAMPLE DESIGN SCHEME 2-DIMENSIONAL SYNCHRONOUS SPECTROSCOPY INFRARED CORRELATION SPECTROSCOPY DIPOLE-DIPOLE INTERACTIONS ASYNCHRONOUS SPECTROSCOPY CROSS PEAKS CONCENTRATION SERIES SOLUTION MIXTURES ORGANIC-LIGANDS IR SPECTROSCOPY |
英文摘要 | Intermolecular interaction between diethyl ether and dichloromethane was investigated by using double asynchronous orthogonal sample design (DAOSD) scheme. FT-IR spectra of the two compounds were measured in the gas phase. A gas cell that satisfied the requirement of the DAOSD approach was designed, fabricated and utilized. The appearance of cross peaks in a pair of asynchronous spectra demonstrated that intermolecular interaction occurred between two compounds. Interference from the spectra of solvent can be avoided by measuring the samples in gas phase, thereby extending the application range of DAOSD and relevant approaches. (C) 2015 Elsevier B.V. All rights reserved.; SCI(E); CPCI-S(ISTP); xyz@pku.edu.cn; ,SI; 244-248; 1124 |
语种 | 英语 |
出处 | 8th International Symposium on Two-Dimensional Correlation Spectroscopy (2DCOS) |
DOI标识 | 10.1016/j.molstruc.2015.12.015 |
内容类型 | 其他 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/456887] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Chen, Mo,Guo, Ran,Zhao, Ying,et al. Investigation on the intermolecular interaction between diethyl ether and dichloromethane in gaseous phase by using the DAOSD approach. 2016-01-01. |
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