Chiral Boron Complex-Promoted Asymmetric Diels-Alder Cycloaddition and   Its Application in Natural Product Synthesis

doi:10.1021/acs.joc.5b02248

CORC > 北京大学 > 化学与分子工程学院

	Chiral Boron Complex-Promoted Asymmetric Diels-Alder Cycloaddition and Its Application in Natural Product Synthesis
	Li, Xia ; Han, Jianguang ; Jones, Alexander X. ; Lei, Xiaoguang
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2016
关键词	CULTIVATED MULBERRY TREE MORUS-ALBA L ENANTIOSELECTIVE TOTAL-SYNTHESIS BOESENBERGIA-PANDURATA BRONSTED ACIDS BROSIMOPSIS-OBLONGIFOLIA MORACEOUS PLANTS ROOT BARK CONSTITUENTS DERIVATIVES
DOI	10.1021/acs.joc.5b02248
英文摘要	An efficient method for the asymmetric Diels-Alder cycloaddition of 2'-hydroxychalcones with acyclic or cyclic dienes has been successfully developed. The Diels-Alder cycloaddition is mediated by a chiral boron complex with VANOL, affording the corresponding products in high yields and with excellent diastereo- and enantioselectivities. This reaction enabled the enantioselective construction of cyclohexene skeletons crucial for the total synthesis of a number of Diels-Alder-type natural products (-)-nicolaioidesin C, (-)-panduratine A, (-)-kuwanon I, (+)-kuwanon J, and (-)-brosimones A and B.; National High Technology Projects 973 [2015CB856200]; NNSFC [21222209, 91313303, 21472010]; SCI(E); ARTICLE; xglei@pku.edu.cn; 2; 458-468; 81
语种	中文
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/438793]
专题	化学与分子工程学院生命科学学院
推荐引用方式 GB/T 7714	Li, Xia,Han, Jianguang,Jones, Alexander X.,et al. Chiral Boron Complex-Promoted Asymmetric Diels-Alder Cycloaddition and Its Application in Natural Product Synthesis[J]. JOURNAL OF ORGANIC CHEMISTRY,2016.
APA	Li, Xia,Han, Jianguang,Jones, Alexander X.,&Lei, Xiaoguang.(2016).Chiral Boron Complex-Promoted Asymmetric Diels-Alder Cycloaddition and Its Application in Natural Product Synthesis.JOURNAL OF ORGANIC CHEMISTRY.
MLA	Li, Xia,et al."Chiral Boron Complex-Promoted Asymmetric Diels-Alder Cycloaddition and Its Application in Natural Product Synthesis".JOURNAL OF ORGANIC CHEMISTRY (2016).