Stable Pt Single Atoms and Nanoclusters on Ultrathin CuO Film and Their   Performances in CO Oxidation

doi:10.1021/acs.jpcc.5b11362

CORC > 北京大学 > 化学与分子工程学院

	Stable Pt Single Atoms and Nanoclusters on Ultrathin CuO Film and Their Performances in CO Oxidation
	Zhou, Xiong ; Yang, Wenshao ; Chen, Qiwei ; Geng, Zhenhua ; Shao, Xiang ; Li, Jianlong ; Wang, Yongfeng ; Dai, Dongxu ; Chen, Wei ; Xu, Guoqin ; Yang, Xueming ; Wu, Kai
刊名	JOURNAL OF PHYSICAL CHEMISTRY C
	2016
关键词	ONE-DIMENSIONAL SUBSTRATE CARBON-MONOXIDE CATALYTIC-OXIDATION MODEL CATALYST ACTIVE GOLD IN-SITU CLUSTERS MECHANISM SURFACES RECONSTRUCTION
DOI	10.1021/acs.jpcc.5b11362
英文摘要	A series of model catalysts consisting of Pt single atoms and nanoclusters supported by monolayered CuO film grown at Cu(110) were successfully prepared, which could be stabilized well above room temperature and which exhibited a high performance in CO oxidation at temperatures as low as similar to 360 K. Combined scanning tunneling microscopy and temperature-programmed desorption measurements directly evidenced that at the initial CO oxidation stage, oxygen vacancy in the CuO lattice was generated at the nearest neighbor of the Pt nanoclusters. The experimental measurements showed that the oxidation activity was inversely proportional to the Pt nanocluster size. In contrast, the Pt single atoms possessed no surface reactivity for the CO oxidation because of the early and complete desorption of CO before its oxidation on the model catalysts commenced.; NSFC [91527303, 21333001, 21133001, 21261130090, 21228301]; MOST, China [2013CB933404, 2011CB808702]; NRF CREATE-SPURc project, Singapore [R-143-001-205-592]; SCI(E); EI; ARTICLE; shaox@ustc.edu.cn; xmyang@dicp.ac.cn; kaiwu@pku.edu.cn; 3; 1709-1715; 120
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/437786]
专题	化学与分子工程学院信息科学技术学院
推荐引用方式 GB/T 7714	Zhou, Xiong,Yang, Wenshao,Chen, Qiwei,et al. Stable Pt Single Atoms and Nanoclusters on Ultrathin CuO Film and Their Performances in CO Oxidation[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2016.
APA	Zhou, Xiong.,Yang, Wenshao.,Chen, Qiwei.,Geng, Zhenhua.,Shao, Xiang.,...&Wu, Kai.(2016).Stable Pt Single Atoms and Nanoclusters on Ultrathin CuO Film and Their Performances in CO Oxidation.JOURNAL OF PHYSICAL CHEMISTRY C.
MLA	Zhou, Xiong,et al."Stable Pt Single Atoms and Nanoclusters on Ultrathin CuO Film and Their Performances in CO Oxidation".JOURNAL OF PHYSICAL CHEMISTRY C (2016).