Pyrazolate-Based Porphyrinic Metal-Organic Framework with Extraordinary   Base-Resistance

doi:10.1021/jacs.5b10881

CORC > 北京大学 > 化学与分子工程学院

	Pyrazolate-Based Porphyrinic Metal-Organic Framework with Extraordinary Base-Resistance
	Wang, Kecheng ; Lv, Xiu-Liang ; Feng, Dawei ; Li, Jian ; Chen, Shuangming ; Sun, Junliang ; Song, Li ; Xie, Yabo ; Li, Jian-Rong ; Zhou, Hong-Cai
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2016
关键词	HIGH-SURFACE-AREA CARBON-DIOXIDE CAPTURE STABILITY NETS MOFS ADSORPTION SEPARATION CATALYSIS CRYSTALS EXCHANGE
DOI	10.1021/jacs.5b10881
英文摘要	Guided by a top-down topological analysis, a metal-organic framework (MOF) constructed by pyrazolate-based porphyrinic ligand, namely, PCN-601, has been rationally designed and synthesized, and it exhibits excellent stability in alkali solutions. It is, to the best of our knowledge, the first identified MOF that can retain its crystallinity and porosity in saturated sodium hydroxide solution (similar to 20 mol/L) at room temperature and 100 degrees C. This almost pushes base-resistance of porphyrinic MOFs (even if MOFs) to the limit in aqueous media and greatly extends the range of their potential applications. In this work, we also tried to interpret the stability of PCN-601 from both thermodynamic and kinetic perspectives.; Natural Science Foundation of China [21322601, 21576006, 21271015, U1407119]; Program for New Century Excellent Talents in University of China [NCET-13-0647]; Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, and Office of Basic Energy Sciences [DE-SC0001015]; SCI(E); EI; PubMed; ARTICLE; jrli@bjut.edu.cn; zhou@chem.tamu.edu; 3; 914-919; 138
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/435574]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Kecheng,Lv, Xiu-Liang,Feng, Dawei,et al. Pyrazolate-Based Porphyrinic Metal-Organic Framework with Extraordinary Base-Resistance[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2016.
APA	Wang, Kecheng.,Lv, Xiu-Liang.,Feng, Dawei.,Li, Jian.,Chen, Shuangming.,...&Zhou, Hong-Cai.(2016).Pyrazolate-Based Porphyrinic Metal-Organic Framework with Extraordinary Base-Resistance.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY.
MLA	Wang, Kecheng,et al."Pyrazolate-Based Porphyrinic Metal-Organic Framework with Extraordinary Base-Resistance".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016).