Low-temperature heat capacity and standard thermodynamic functions of beta-D-(-)-arabinose (C5H10O5) | |
Dai, Ruxi ; Zhang, Shihui ; Yin, Nan ; Tan, Zhi-Cheng ; Shi, Quan | |
刊名 | JOURNAL OF CHEMICAL THERMODYNAMICS
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2016 | |
关键词 | beta-D-(-)-arabinose Low-temperature heat capacity Standard thermodynamic functions Physical Property Measurement System T=298.15 K ARABINOSE VOLUMES WATER CALORIMETER SACCHARIDES GLUCOSE COPPER |
DOI | 10.1016/j.jct.2015.08.031 |
英文摘要 | The heat capacities of beta-D-(-)-arabinose were measured using a Quantum Design Physical Property Measurement System (PPMS) over the temperature range from (1.9 to 300) K, and the experimental values were fitted as a function of temperature using a series of theoretical and empirical models in the appropriate temperature ranges, from which the corresponding thermodynamic functions were calculated. The standard molar heat capacity, entropy and enthalpy of beta-D-(-)-arabinose at T = 298.15 K and P = 0.1 MPa were determined to be C-p,m(o) = (186.29 +/- 1.86) J . K-1 . mol(-1), S-m(o) = (181.72 +/- 1.83) J . K-1 . mol(-1) and H-m(o) = (28.52 +/- 0.29) kJ . mol(-1), respectively. (C) 2015 Elsevier Ltd. All rights reserved.; National Natural Science Foundation of China under the NSFC [21473198]; SCI(E); EI; ARTICLE; tzc@dicp.ac.cn; shiquan@dicp.ac.cn; 60-65; 92 |
语种 | 中文 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/422664] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Dai, Ruxi,Zhang, Shihui,Yin, Nan,et al. Low-temperature heat capacity and standard thermodynamic functions of beta-D-(-)-arabinose (C5H10O5)[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2016. |
APA | Dai, Ruxi,Zhang, Shihui,Yin, Nan,Tan, Zhi-Cheng,&Shi, Quan.(2016).Low-temperature heat capacity and standard thermodynamic functions of beta-D-(-)-arabinose (C5H10O5).JOURNAL OF CHEMICAL THERMODYNAMICS. |
MLA | Dai, Ruxi,et al."Low-temperature heat capacity and standard thermodynamic functions of beta-D-(-)-arabinose (C5H10O5)".JOURNAL OF CHEMICAL THERMODYNAMICS (2016). |
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