Ammonia borane confined by nitrogen-containing carbon nanotubes:   enhanced dehydrogenation properties originating from synergetic   catalysis and nanoconfinement

doi:10.1039/c5ta05540g

CORC > 北京大学 > 化学与分子工程学院

	Ammonia borane confined by nitrogen-containing carbon nanotubes: enhanced dehydrogenation properties originating from synergetic catalysis and nanoconfinement
	Zhang, Lijun ; Xia, Guanglin ; Ge, Yu ; Wang, Caiyun ; Guo, Zaiping ; Li, Xingguo ; Yu, Xuebin
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2015
关键词	CHEMICAL HYDROGEN STORAGE METAL-ORGANIC-FRAMEWORK THERMAL-DECOMPOSITION HIGHLY EFFICIENT RELEASE METHANOL H-2 HYDRIDES NANOCOMPOSITES BOROHYDRIDES
DOI	10.1039/c5ta05540g
英文摘要	Borane-amine adducts (H3N center dot BH3, AB) in tetrahydrofuran solution were infiltrated into polypyrrole (PPy) nanotubes by a capillary effect, forming an ammonia borane (AB)@PPy combined system. This composite system combines the synergetic catalysis of nitrogen atoms with nanoconfinement in nanotubes, resulting in a significant improvement in the dehydrogenation properties. Dehydrogenation results showed that the AB loaded on PPy can release 15.3% hydrogen below 150 degrees C with an onset decomposition temperature as low as 48 degrees C. More importantly, the evolution of harmful ammonia, diborane, and borazine was entirely suppressed.; National Natural Science Foundation of China [21271046, 51471053]; PhD Programs Foundation of the Ministry of Education of China [20110071110009]; Australian Research Council Centre of Excellence Scheme [CE 140100012]; SCI(E); EI; ARTICLE; zguo@uow.edu.au; yuxuebin@fudan.edu.cn; 41; 20494-20499; 3
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/420999]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Lijun,Xia, Guanglin,Ge, Yu,et al. Ammonia borane confined by nitrogen-containing carbon nanotubes: enhanced dehydrogenation properties originating from synergetic catalysis and nanoconfinement[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015.
APA	Zhang, Lijun.,Xia, Guanglin.,Ge, Yu.,Wang, Caiyun.,Guo, Zaiping.,...&Yu, Xuebin.(2015).Ammonia borane confined by nitrogen-containing carbon nanotubes: enhanced dehydrogenation properties originating from synergetic catalysis and nanoconfinement.JOURNAL OF MATERIALS CHEMISTRY A.
MLA	Zhang, Lijun,et al."Ammonia borane confined by nitrogen-containing carbon nanotubes: enhanced dehydrogenation properties originating from synergetic catalysis and nanoconfinement".JOURNAL OF MATERIALS CHEMISTRY A (2015).