| Thermal and light induced spin crossover behavior of a dinuclear Fe(II) compound | |
| Cheng, Xin ; Yang, Qian ; Gao, Chen ; Wang, Bing-Wu ; Shiga, Takuya ; Oshio, Hiroki ; Wang, Zhe-Ming ; Gao, Song | |
| 刊名 | DALTON TRANSACTIONS
 |
| 2015 | |
| 关键词 | MAGNETIC-PROPERTIES 1,2,4-TRIAZOLE COMPLEXES CRYSTAL-STRUCTURE ROOM-TEMPERATURE TRANSITION HYSTERESIS |
| DOI | 10.1039/c5dt01755f |
| 英文摘要 | A dinuclear Fe(II) compound has been prepared through the reaction of 2,5-dichloride-4-phenylimino-1,2,4-triazole (L) with Fe(BF4)(2)center dot 6H(2)O, with the formula [Fe-2(L)(5)(SCN)(4)](H2O) (1). X-ray, magnetic, and Fe-57 Mossbauer characterizations showed that compound 1 exhibited a spin crossover (SCO) behavior with T-1/2 = 150 K. The study shows that introducing chloride groups on the ligand exerts a positive effect on increasing T-1/2 and making SCO more complete. A LIESST effect was also observed for 1 through a light irradiation experiment.; Natural Science Foundation of China [21290171, 21321001]; National Basic Research Program [2013CB933401]; SCI(E); EI; PubMed; ARTICLE; wangbw@pku.edu.cn; gaosong@pku.edu.cn; 25; 11282-11285; 44 |
| 语种 | 英语 |
| 内容类型 | 期刊论文 |
| 源URL | [http://ir.pku.edu.cn/handle/20.500.11897/419407]  |
| 专题 | 化学与分子工程学院 |
| 推荐引用方式 GB/T 7714 | Cheng, Xin,Yang, Qian,Gao, Chen,et al. Thermal and light induced spin crossover behavior of a dinuclear Fe(II) compound[J]. DALTON TRANSACTIONS,2015. |
| APA | Cheng, Xin.,Yang, Qian.,Gao, Chen.,Wang, Bing-Wu.,Shiga, Takuya.,...&Gao, Song.(2015).Thermal and light induced spin crossover behavior of a dinuclear Fe(II) compound.DALTON TRANSACTIONS. |
| MLA | Cheng, Xin,et al."Thermal and light induced spin crossover behavior of a dinuclear Fe(II) compound".DALTON TRANSACTIONS (2015). |
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