Synthesis of 5-Fluorotriazoles by Silver-Mediated Fluorination of   5-Iodotriazoles

doi:10.1002/ejoc.201500338

CORC > 北京大学 > 化学与分子工程学院

	Synthesis of 5-Fluorotriazoles by Silver-Mediated Fluorination of 5-Iodotriazoles
	Wang, Damin ; Sun, Wenjing ; Chu, Taiwei
刊名	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
	2015
关键词	Heterocycles Fluorine Halogenation Silver COPPER-CATALYZED CYCLOADDITION COUPLING REACTION TERMINAL ALKYNES CLICK CHEMISTRY ARYL STANNANES ORGANIC AZIDES 1,2,3-TRIAZOLES FLUORIDE TRIFLUOROMETHYLATION PALLADIUM
DOI	10.1002/ejoc.201500338
英文摘要	A simple method was developed for the direct fluorination of 5-iodotriazoles with AgF as fluoride source and N-1,N-1,N-2,N-2-tetramethylethane-1,2-diamine (TMEDA) as ligand. This method is compatible with various functional groups. 5-Iodotriazoles without aromatic groups at the 4-position or aliphatic substituents at the N1 position can also be smoothly converted to the corresponding 5-fluorotriazoles. Preliminary mechanism studies were also performed.; National Natural Science Foundation of China [21371017]; SCI(E); ARTICLE; twchu@pku.edu.cn; 19; 4114-4118
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/418914]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Damin,Sun, Wenjing,Chu, Taiwei. Synthesis of 5-Fluorotriazoles by Silver-Mediated Fluorination of 5-Iodotriazoles[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2015.
APA	Wang, Damin,Sun, Wenjing,&Chu, Taiwei.(2015).Synthesis of 5-Fluorotriazoles by Silver-Mediated Fluorination of 5-Iodotriazoles.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY.
MLA	Wang, Damin,et al."Synthesis of 5-Fluorotriazoles by Silver-Mediated Fluorination of 5-Iodotriazoles".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2015).