Temperature-Responsive Chiral (A)(6)B Supramolecular Cages Based on   Conformational Preferences

doi:10.1002/asia.201501090

CORC > 北京大学 > 化学与分子工程学院

	Temperature-Responsive Chiral (A)(6)B Supramolecular Cages Based on Conformational Preferences
	Chen, Shi-Gui ; Zhao, Zhi-Xiong ; Jiang, Xiao-Nan ; Wang, Lu ; Zhou, Tian-You ; Lu, Cheng-Lu ; Zhao, Xin ; Jiang, Xi-Kui ; Ma, Yuguo ; Wang, Ren-Xiao ; Li, Zhan-Ting
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2016
关键词	chiral transfer conformational chirality conformational preference supramolecular cages temperature-responsive HYDROGEN-BONDING MOTIF MOLECULAR RECOGNITION POLYMER NETWORK VESICLES ASSEMBLIES RELEASE COPOLYMERS LIGHT NANOPARTICLES AMPHIPHILES
DOI	10.1002/asia.201501090
英文摘要	Two chiral (A)(6)B-typed supramolecular cages were constructed from hydrogen-bonded C-6-symmetric zinc porphyrin hexamers and chiral C-3-symmetric pyridyl hexadentates with a core of 1,3,5-triphenylbenzene. Circular dichroism and molecular simulations revealed that the symmetry of the supramolecular cages switched from pseudo-C-3v to C-3 with the rotational confinement of the biphenyl backbones at low temperatures, which generated conformationally chiral transfer and amplification. This unique phenomenon suggests a new strategy to develop smart materials with high sensitivity and excellent reversibility.; National Natural Science Foundation [91227108, 21172249]; Ministry of Science and Technology of China [2013CB834501]; SCI(E); EI; PubMed; ARTICLE; xzhao@mail.sioc.ac.cn; ygma@pku.edu.cn; wangrx@mail.sioc.ac.cn; ztli@mail.sioc.ac.cn; 4; 465-469; 11
语种	中文
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/416508]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Chen, Shi-Gui,Zhao, Zhi-Xiong,Jiang, Xiao-Nan,et al. Temperature-Responsive Chiral (A)(6)B Supramolecular Cages Based on Conformational Preferences[J]. CHEMISTRY-AN ASIAN JOURNAL,2016.
APA	Chen, Shi-Gui.,Zhao, Zhi-Xiong.,Jiang, Xiao-Nan.,Wang, Lu.,Zhou, Tian-You.,...&Li, Zhan-Ting.(2016).Temperature-Responsive Chiral (A)(6)B Supramolecular Cages Based on Conformational Preferences.CHEMISTRY-AN ASIAN JOURNAL.
MLA	Chen, Shi-Gui,et al."Temperature-Responsive Chiral (A)(6)B Supramolecular Cages Based on Conformational Preferences".CHEMISTRY-AN ASIAN JOURNAL (2016).