Construct Polyoxometalate Frameworks through Covalent Bonds

doi:10.1021/acs.inorgchem.5b01326

CORC > 北京大学 > 化学与分子工程学院

	Construct Polyoxometalate Frameworks through Covalent Bonds
	Chen, Hong ; Zhao, Huishuang ; Yu, Zheng-Bao ; Wang, Lei ; Sun, Licheng ; Sun, Junliang
刊名	INORGANIC CHEMISTRY
	2015
关键词	METAL-ORGANIC FRAMEWORK DESIGNED SYNTHESIS MASS-SPECTROMETRY BUILDING-BLOCKS HIGH-NUCLEARITY SINGLE-CRYSTAL CLUSTERS COMPLEXES MOLYBDENUM OXIDATION
DOI	10.1021/acs.inorgchem.5b01326
英文摘要	An emerging strategy for exploring the application of polyoxometalates (POMs) is to assemble POM clusters into open-framework materials, especially inorganic organic hybrid three-dimensional (3D) open-framework materials, via the introduction of different organic linkers between the POM clusters. This strategy has yielded a few 3D crystalline POMs of which a typical class is the group of polyoxometalate metal organic frameworks (POMMOFs). However, for reported POMMOFs, only coordination bonds are involved between the linkers and POM clusters, and it has not yet produced any covalently bonded polyoxometalate frameworks. Here, the concept of "covalently bonded POMs (CPOMs)" is developed. By using vanadoborates as an example, we showed that the 3D CPOMs can be obtained by a condensation reaction through the oxolation mechanism of polymer chemistry. In particular, suitable single crystals were harvested and characterized by single-crystal X-ray diffraction. This work forges a link among polymer science, POM chemistry, and open-framework materials by demonstrating that it is possible to use covalent bonds according to polymer chemistry principles to construct crystalline 3D open-framework POM materials.; Swedish Research Council (VR); Swedish Governmental Agency for Innovation Systems (VINNOVA) through Berzelii EXSELENT; National Basic Research Program of China [2013CB933402]; National Natural Science Fundation [21321001, 21471009]; SCI(E); PubMed; ARTICLE; junliang.sun@pku.edu.cn; 17; 8699-8704; 54
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/416348]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Chen, Hong,Zhao, Huishuang,Yu, Zheng-Bao,et al. Construct Polyoxometalate Frameworks through Covalent Bonds[J]. INORGANIC CHEMISTRY,2015.
APA	Chen, Hong,Zhao, Huishuang,Yu, Zheng-Bao,Wang, Lei,Sun, Licheng,&Sun, Junliang.(2015).Construct Polyoxometalate Frameworks through Covalent Bonds.INORGANIC CHEMISTRY.
MLA	Chen, Hong,et al."Construct Polyoxometalate Frameworks through Covalent Bonds".INORGANIC CHEMISTRY (2015).