FT-IR study of the coordination of an organophosphonic acid with lanthanide ions | |
Wang, DJ ; Yao, SX ; Wu, JG ; Shi, N ; Zhang, X ; Xu, GX | |
1997 | |
关键词 | FT-IR coordination microemulsion extraction lanthanides EXTRACTION |
英文摘要 | The coordination interaction between saponified 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEHEHP) with lanthanide ions [Ln(III)] in an extracted organic phase has been studied by FT-IR spectral analysis. The result indicates that with the increase of lanthanide loading in the organic phase, the microstructure of the water/oil microemulsions formed by the saponified extractant is gradually destroyed. The P=O group of the extractant was found to coordinate with the Ln(III). The coordination ability of the lanthanide series with the P=O group was found to increase from La(III) to Pr(III), but decrease from Pr(III) to Lu(III).; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:A1997WW40400052&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Analytical; SCI(E); 0 |
语种 | 英语 |
内容类型 | 其他 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/401961] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Wang, DJ,Yao, SX,Wu, JG,et al. FT-IR study of the coordination of an organophosphonic acid with lanthanide ions. 1997-01-01. |
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